高熵合金反应共烧保护层/接触层双层结构在SOFC阴极侧的应用  

Co-Sintering of High-entropy Alloy Derived Coating/Contact Dual-Layer Structure for Application of SOFC at Cathode-Side

作　　者：陈帮富 陈云霞 余喻天 吴博 林囿辰 刘青 关成志[2] 王建强[2] CHEN Bangfu;CHEN Yunxia;YU Yutian;WU Bo;LIN Youchen;LIU Qing;GUAN Chengzhi;WANG Jianqiang(School of Materials Science and Engineering,Jingdezhen Ceramic University,Jingdezhen 333403,Jiangxi,China;Department of Hydrogen Energy Technology,Shanghai Institute of Applied Physics,Chinese Academy of Science,Shanghai 201800,China;College of Science,Shenyang University of Chemical Technology,Shenyang 110027,Liaoning,China;Shanghai EGEN Energy Technology Co.,Ltd.,Shanghai 201800,China)

机构地区：[1]景德镇陶瓷大学材料科学与工程学院,江西景德镇333403 [2]中国科学院上海应用物理研究所氢能技术部,上海201800 [3]沈阳化工大学理学院,辽宁沈阳110027 [4]上海翌晶氢能科技有限公司,上海201800

出　　处：《陶瓷学报》2025年第1期96-105,共10页Journal of Ceramics

基　　金：中国科学院前瞻战略科技先导专项(XDA0400000);上海市嘉定区科技创新“揭榜挂帅”项目;上海市2023年度“科技创新行动计划”科技支撑碳达峰碳中和项目(23DZ1201803);江西省科技合作计划重点项目(20212BDH80005);上海市科技计划项目(21DZ1207700)。

摘　　要：铁素体不锈钢是固体氧化物燃料电池(Solid Oxide Fuel Cell,SOFC)中常用的连接体材料,但是不锈钢合金在SOFC的工作温度(600℃~850℃)下仍存在表面高温氧化、Cr元素“毒化”阴极以及连接体与阴极接触面积不充分等问题。针对以上难题,本研究选用MnCoNiFeCu合金粉末作为致密保护层和多孔接触层的前驱材料,合成浆料后丝网印刷至SUS 430表面上并在900℃空气烧结2 h,分别研究了保护层和接触层在烧结之后的相组成和微观结构演变。在模拟的SUS 430连接体/保护层/接触层/电池阴极/阴极支撑测试样品中,通过反应共烧制备了高熵尖晶石基保护层和接触层的双层结构。在1000 h恒温面电阻(Area-Specific Resistance,ASR)测试中,样品ASR值稳定保持在22.04 mΩ·cm^(2)~22.71 mΩ·cm^(2),而热循环测试导致样品ASR急剧增加。通过对测试样品横截面的分析,研究了高熵尖晶石基双层结构与相邻组件的相容性以及热稳定性。此外,还评估了高熵尖晶石基双层结构抑制Cr_(2)O_(3)膜的生长和阻止Cr从连接体向阴极迁移的有效性。[Background and purpose]Solid oxide fuel cell(SOFC)is a highly efficient electrochemical device that can be used to directly convert chemical energy of hydrogen and hydrocarbon fuels into electricity in an environmentally friendly manner.While the typical operating temperatures of SOFCs have been reduced to 600–850℃,ferritic stainless steels(FSS),such as ZMG 232,AISI 441,SUS430,etc.,can be utilized as interconnect materials,due to their high electrical conductivity,low material/manufacturing cost,excellent mechanic strength and similar coefficient of thermal expansion(CTE)to other cell components.However,it still exists several issues during their operation at 600–850℃,including continuous growth of Cr_(2)O_(3) scale,Cr migration to cathode and dimensional tolerance at interconnect-cathode interface.These issues will cause serious performance degradation for stacks.To solve these problems,a dense protective coating and a porous contact layer are typically prepared between the metallic interconnect and the cathode.The dense protective coating is utilized to inhibit the growth of Cr_(2)O_(3) scale and prevent Cr migration to the cathode,while the porous contact layer can provide better electrical pathway to decrease the power losses and compensate for the dimensional tolerance between the interconnect and the cathode.[Methods]In this study,MnCoNiFeCu alloy powder was selected as the precursor materials for dense protective coating and porous contact layer.A coating/contact dual-layer structure was fabricated through reactive co-sintering in the simulated SUS 430 interconnect/coating/contact/cathode/cathode support test cells.The precursors were calcined in air at 900℃for 2 h to study phase evolution and microstructure of the protective coating and the contact layer.The phases in the sintered layers were characterized by using X-ray diffraction(XRD),whereas scanning electron microscopy(SEM)featured with energy-dispersive spectroscopy(EDS)was utilized to analyze the microstructure and obtain the composition

关 键 词：固体氧化物燃料电池 高熵尖晶石 反应共烧 尖晶石 双层结构 

分 类 号：TQ174.75[化学工程—陶瓷工业]