金属-有机框架光催化还原CO_(2)为C1产物研究进展  

Research progress in photocatalytic reduction of CO_(2) to C1 product by metal-organic framework

作　　者：赵思思 王新宇 赵经纬 王瑞 张航 孙琪 赵震 Si-Si Zhao;Xinyu Wang;Jingwei Zhao;Rui Wang;Hang Zhang;Qi Sun;Zhen Zhao(Institute of Catalysis for Energy and Environment,College of Chemistry and Chemical Engineering,Shenyang Normal University,Shenyang 110034,China)

机构地区：[1]沈阳师范大学化学化工学院,能源与环境催化研究所,沈阳110034

出　　处：《中国科学:化学》2025年第2期319-344,共26页SCIENTIA SINICA Chimica

基　　金：国家自然科学基金青年科学基金(编号:22109105,22102106);辽宁省“兴辽英才计划”(编号:XLYC2203120)资助项目。

摘　　要：利用清洁可再生的太阳能将CO_(2)光催化还原为高附加值化学品是解决能源和环境问题的一条非常有前景的途径.MOF具有结构明确、可修饰性强以及良好的CO_(2)捕获能力,近年来在光催化还原CO_(2)中得到了广泛的应用.本综述按照MOF材料光催化还原CO_(2)的C1产物进行了分类讨论,特别强调了MOF材料在吸光、材料设计及捕集CO_(2)的能力对光催化CO_(2)还原性能的作用.此外,介绍了较为典型的MOF在光催化还原CO_(2)成C1产物所取得的研究进展,提出了MOF材料在光催化CO_(2)转化中应用的机遇、挑战和未来前景,旨在以绿色和可持续的策略合理设计更具创造性的MOF光催化CO_(2)体系.The photocatalytic reduction of carbon dioxide(CO_(2))to high value-added chemicals using clean and renewable solar energy is a very promising way to solve energy and environmental problems.Metal-organic framework(MOF)has been widely used in photocatalytic reduction of CO_(2) in recent years because of its regular structure,strong modifiability and excellent carbon dioxide capture ability.In this review,the C1 products of photocatalytic reduction of CO_(2) by MOF–based material are classified and discussed,with special emphasis on the role of MOF materials in light absorption,material design and CO_(2) capture ability on photocatalytic CO_(2) reduction performance.In addition,the research progress of typical MOF in photocatalytic reduction of CO_(2) to C1 products is introduced,and the opportunities,challenges and future prospects of the application of MOF-based materials in photocatalytic CO_(2) conversion are put forward.The purpose is to reasonably design a more creative MOF-based photocatalytic system for CO_(2) utilization with a green and sustainable strategy.

关 键 词：光催化 金属-有机框架 CO_(2)还原 C1产物 

分 类 号：O64[理学—物理化学]