纳米级ZSM-5绿色合成研究进展  

Research progress in green synthesis of nano-sized ZSM-5

作　　者：褚金洋 王家亮 杜丹阳 张红丹 程鹏 Jinyang Chu;Jialiang Wang;Danyang Du;Hongdan Zhang;Peng Cheng(Institute of Catalysis for Energy and Environment,College of Chemistry and Chemical Engineering,Shenyang Normal University,Shenyang 110034,China)

机构地区：[1]沈阳师范大学化学化工学院,能源与环境催化研究所,沈阳110034

出　　处：《中国科学:化学》2025年第2期345-357,共13页SCIENTIA SINICA Chimica

基　　金：国家自然科学基金(编号:22172102,22202137);辽宁省基本科研项目(编号:LJ202410166003,LJ202410166021);大学生创新创业训练计划资助项目。

摘　　要：纳米级ZSM-5是一种具有高催化活性和高稳定性的沸石,在工业生产的各个领域发挥着重要的作用.但在传统的合成过程中,大量价格昂贵且不宜回收有机模板剂的使用及长时间晶化造成的高能耗限制了纳米级ZSM-5的应用并对环境造成了一定的污染.此外,高温导致反应釜体系压强过大,形成了一定的安全隐患.因此,开发纳米级ZSM-5沸石绿色合成策略具有重要的意义.本文从“绿色化学”原则的角度出发,系统地阐述了近10年纳米级ZSM-5的绿色合成方法,对比了不同绿色合成方法的优势与局限性,并对其未来发展前景进行了展望.As a type of zeolite with high catalytic activity and high stability,nano ZSM-5 plays an important role in various fields of industry.However,a large amount of expensive and non-recyclable organic templates,as well as the high energy consumption caused by long-term crystallization,limit the application of nano ZSM-5 and cause environmental pollution.In addition,high temperature leads to excessive pressure in autoclave,posing safety hazard.Therefore,developing green synthesis strategies for nano ZSM-5 zeolite is of great significance.In this review,green synthesis methods of nano ZSM-5 in recent years are systematically described based on“green chemistry”principles.The advantages and limitations of different green synthesis methods are compared,and their development directions are prospected.

关 键 词：纳米ZSM-5 绿色合成 晶化时间 低能耗 结晶度 

分 类 号：TB383.1[一般工业技术—材料科学与工程] O643.36[理学—物理化学]