Viscosity,NMR Diffusometry and Light Scattering Data for Aqueous and Aqueous-Salt Solutions of Poly(1-butyl-3-vinylimidazolium bromide)  

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作  者:Petr A.Korchak Polina S.Yarchenko Evgenia A.Safonova Alina S.Koneva Alexey I.Victorov 

机构地区:[1]St.Petersburg State University,St.Petersburg 199034,Russia

出  处:《Chinese Journal of Polymer Science》2025年第2期380-391,共12页高分子科学(英文版)

基  金:financially supported by the Russian Science Foundation(No.20-13-00038).

摘  要:Poly(1-butyl-3-vinylimidazolium bromide)is a polymerized ionic liquid(PILs),a relatively new class of materials that combines the attractive properties of ionic liquids(ILs)and polyelectrolytes and finds wide applications.The backbone of this PIL is composed of quaternary imidazolium salts,which are among the most promising and popular ILs.However,little is known about the physicochemical characteristics of the aqueous solutions of this PIL.In this study,we synthesized and characterized samples of this PIL and obtained experimental data on the viscosity,static and dynamic light scattering,and nuclear magnetic resonance diffusometry for aqueous and aqueous KBr solutions with varying polymer contents at T=298.15 K.We discuss the effects of the polymer concentration and salinity on the behavior of the solution.

关 键 词:Polymerized ionic liquid Polyelectrolyte solutions VISCOSITY Light scattering NMR diffusometry 

分 类 号:O63[理学—高分子化学]

 

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