Tailoring solvation sheath for rechargeable zinc-ion batteries:Progress and prospect  

作　　者：Xiaomin Cheng Jing Dong Haifeng Yang Xiang Li Xinyu Zhao Bixian Chen Yongzheng Zhang Meinan Liu Jian Wang Hongzhen Lin 

机构地区：[1]i-Lab&CAS Key Laboratory of Nanophotonic Materials and Devices,Suzhou Institute of Nano-Tech and Nano-Bionics,Chinese Academy of Sciences,Suzhou,215123,China [2]State Key Laboratory of Chemical Engineering,East China University of Science and Technology,Shanghai,200237,China [3]Anhui Provincial Key Laboratory of Green Carbon Chemistry,Fuyang Normal University,Fuyang,236037,China [4]State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures,Guangxi Key Laboratory of Processing for Non-Ferrous Metals and Featured Materials,School of Resources,Environment and Materials,Guangxi University,Nanning,530004,China [5]Helmholtz Institute Ulm(HIU),D89081 Ulm,Karlsruhe Institute of Technology(KIT),D76021 Karlsruhe,Germany [6]School of Materials Science and Engineering,Jiangsu University,Zhenjiang,212013,Jiangsu,China

出　　处：《Materials Reports(Energy)》2025年第1期3-18,共16页材料导报(能源)(英文)

基　　金：financially supported by the National Key Research and Development Program of China(2021YFA1201503);National Natural Science Foundation of China(No.21972164,22279161,and 22309144);the Natural Science Foundation of Jiangsu Province(BK.20210130);Shanghai Sailing Program of China(23YF1408900);China Postdoctoral Science Foundation(No.2024M762318,2023M731084,and 2023M732561);Suzhou Science and Technology Plan project(SYC2022057);Innovative and Entrepreneurial Doctor in Jiangsu Province(JSSCBS20211428);Opening funding from Key Laboratory of Engineering Dielectrics and Its Application(Harbin University of Science and Technology)(No.KFM202507,Ministry of Education);the funding provided by the Alexander von Humboldt Foundation;the Shanghai Super Postdoctoral Incentive Program;the support from Nano-X,Suzhou Institute of Nano-tech and Nano-bionics,Chinese Academy of Sciences.

摘　　要：Aqueous zinc-metal based batteries(AZMBs)perfectly combine safety,economy and pro-environment,but their performance is arresting limited by the interfacial instability caused by the large desolvation energy barrier of[Zn(H2O)6]^(2+)and the massive release of active water at the electrolyte/electrode interface.In this review,we briefly outline the solvation structure of zinc ions and the necessity of desolvation.Subsequently,the variety of strategies to solve these issues,mainly including reorganizing solvation sheath by changing electrolyte environment and accelerating interface desolvation by constructing artificial interfacial layer,are categorically discussed and systematically summarized.Meanwhile,perspectives and suggestions regarding desolvation theories,interfacial evolution,material design and analysis techniques are proposed to design highly stable zinc anodes.

关 键 词：Aqueous zinc-metal based batteries DESOLVATION Electrolyte strategy Interfacial layer 

分 类 号：O64[理学—物理化学]