A novel ultra-high temperature ceramic composite coating prepared by high-speed laser cladding and pack cementation on Ta–W alloys for higher plasma ablation resistance above 2300℃  

作　　者：Youjiang Zhang Qiyao Deng Yang Li Pengfei He Chuan Sun Wengang Bu Yue Xing Yujun Cai Xiubing Liang 

机构地区：[1]National-Local Joint Engineering Laboratory of Intelligent Manufacturing Oriented Automobile Die&Mould,Tianjin University of Technology and Education,Tianjin 300222,China [2]Defense Innovation Institute,Academy of Military Science,Beijing 100071,China

出　　处：《Journal of Advanced Ceramics》2025年第1期111-125,共15页先进陶瓷(英文)

基　　金：supported by the National Natural Science Foundation of China(Nos.52105233 and 52275366).

摘　　要：To improve the high-temperature ablation resistance properties of Ta(W) refractory alloys, a novel ultra-high-temperature ceramic (UHTC) composite coating was prepared by combining the technological advantages of high-speed laser cladding (HSLC) and pack cementation (PC). First, the HSLC process was employed to fabricate a (Hf,Ta)C–Ta(W) UHTC–refractory metal composite coating that had metallurgical bonding with the Ta(W) substrate. Then, the PC process was utilized to transform the refractory metal phase in the coating into the corresponding refractory silicide (RMSi_(2)) phase. Consequently, the (Hf,Ta)C–TaSi_(2) UHTC composite coating was successfully prepared. This new coating was ablated at a heat flux density of 8.0 MW/m^(2) for 300 s at a surface temperature of 2300 ℃, and the structural integrity of the coating was retained. The linear ablation rate of the coating is −0.67 µm/s. The ablated coating exhibits three distinct oxide layers: a loose HfO_(2) top layer, a dense HfO_(2) middle layer, and a slightly oxidized (Hf,Ta)CxOy–Hf–Ta–O glassy layer. The synergistic effect of HfO_(2) and Hf–Ta–O glassy oxide film endows the coating with excellent anti-ablation resistance. This innovative design of the UHTC–RMSi_(2) composite coating provides robust protection to the Ta(W) substrate from ultra-high temperature ablation and mechanical scouring.

关 键 词：high-speed laser cladding pack cementation(PC) Ta-Walloy ultra-high temperature ceramic(UHTC) composite coating ablation resistance 

分 类 号：TQ174.75[化学工程—陶瓷工业] TB33[化学工程—硅酸盐工业]