通过饱和液化石油气分离优化乙烯裂解装置原料  

Optimization of ethylene cracking unit feedstock through saturated liquefied petroleum gas separation

作　　者：孙艳朋 孙渲楦 Sun Yanpeng;Sun Xuanxuan(Strategic Business Unit of Chlor-alkali,Beijing 100080;Liaoning Petrochemical College,Jinzhou,Liaoning 121001)

机构地区：[1]中国中化氯碱事业部,北京市100080 [2]辽宁石化职业技术学院,辽宁省锦州市121001

出　　处：《炼油技术与工程》2025年第2期36-40,共5页Petroleum Refinery Engineering

摘　　要：某大型炼化公司装置受饱和液化石油气输储流程限制,导致混合饱和液化石油气中异丁烷含量偏高,影响乙烯收率。通过分析饱和液化石油气组成,对比分析前脱丙烷流程和后脱丙烷流程两种液化石油气分离流程方案的能耗、设备尺寸结果后,新增850 kt/a饱和液化石油气分离装置采用了脱丙烷塔+正异构分离塔+脱乙烷塔三塔流程。结果表明:全装置产品乙烯收率上升8.23百分点,丙烯下降1.65百分点,混合C4及裂解汽油下降5.96百分点;装置综合能耗标定值为29.11 kgoe/t,比设计值低20.42 kgoe/t。装置的脱丙烷塔、正异构分离塔、脱乙烷塔生产操作正常、塔的分离效果能满足正常生产要求,产品质量合格,实现优化乙烯裂解原料、延缓生焦周期并增产乙烯的目标。The unit of a large refining company was limited by the saturated liquefied petroleum gas transportation and storage process,resulting in a high isobutane content in the mixed saturated liquefied petroleum gas,which affected the ethylene yield.By analyzing the composition of saturated liquefied petroleum gas and comparing the energy consumption and equipment size of two liquefied petroleum gas separation processes,front-end de-propanization and back-end de-propanization,the newly built 850 kt/a saturated liquefied petroleum gas separation unit adopted a three tower process of de-propanization tower,isomerization separation tower,and de-ethanation tower.The results showed that the ethylene yield of the entire unit increased by 8.23 percentage points propylene yield decreased by 1.65 percentage points,and the yield of mixed C 4 and cracking gasoline decreased by 5.96 percentage points;the comprehensive energy consumption calibration value of the unit was 29.11 kgoe/t,which was 20.42 kgoe/t lower than the design value.The production operations of the de-propanization tower,isomerization separation tower,and de-ethanation tower of the unit are normal.The separation effect of the towers can meet the normal production requirements.The product quality is qualified,achieving the goal of optimizing the ethylene cracking feedstock,delaying the coking cycle,and increasing ethylene production.

关 键 词：饱和液化石油气 乙烯裂解装置 异丁烷含量 乙烯收率 前脱丙烷 后脱丙烷 能耗 

分 类 号：TQ221.211[化学工程—有机化工] TE96[石油与天然气工程—石油机械设备]