Photothermal-boosted flexible rechargeable zinc-air battery based on Ni-doped Mn_(3)O_(4) with excellent low-temperature adaptability  

作　　者：Wengai Guo Fan Gu Qilin Chen Kexuan Fu Yuqing Zhong Jing‐Jing Lv Shuang Pan Yihuang Chen 

机构地区：[1]College of Chemistry and MaterialsEngineering,Wenzhou University,Wenzhou,Zhejiang,China [2]Institute of New Materials and IndustrialTechnologies,wenzhou University,Wenzhou,China

出　　处：《Carbon Energy》2024年第11期187-200,共14页碳能源(英文)

基　　金：The work was financially supported by the NationalNatural Science Foundation of China(Grant numbers:22109120,62104170, 52331009);the ZhejiangProvincial Natural Science Foundation of China(Grantnumbers:LQ21B030002 , LY23F040001).

摘　　要：As a promising flexible energy source for next-generation emerging electronic devices,the temperature adaptability and low-temperature performance retention of flexible zinc-air batteries(ZABs)remain a great challenge for their practical application.Herein,we report photothermal-promoted aqueous and flexible ZABs with enhanced performance under a wide temperature range via using Ni-doped Mn_(3)O_(4) /N-doped reduced graphene oxide(denoted as Ni-Mn_(3)O_(4) /N-rGO)nanohybrids as bifunctional electrocatalysts.Upon being exposed to near-infrared light,the Ni-Mn_(3)O_(4) /N-rGO exhibited a powerful photothermal effect,resulting in localized and immediate heating of the electrode.Such effects led to increased active sites,improved electrical conductivity,enhanced release of bubbles,and promoted surface reconstruction of the electrode catalyst as corroborated by simulation and operando Raman.Consequently,the catalytic performance was boosted,manifesting a superior activity indicatorΔE of 0.685 V with excellent durability.As expected,the corresponding photothermal-assisted rechargeable ZABs possessed an excellent maximum power density(e.g.,78.76 mW cm^(−2) at−10℃),superb cycling stability(e.g.,over 430 cycles at−10℃),and excellent flexibility from 25℃ to subzero temperature.Our work opens up new possibilities for the development of all-climate flexible electronic devices.

关 键 词：NANOHYBRIDS operando Raman photothermal effect stability wide-temper atureadaptability zinc-air batteries 

分 类 号：O64[理学—物理化学]