Tuning Hydrophilic Segments to Achieve Acid-Free Proton Conduction in COF  

作　　者：Kun Zhang Lei Wu Yanting Zhang Hong Zhang Dongshuang Wu 

机构地区：[1]Automotive Engineering Research Institute,Jiangsu University,301 Xuefu Road,Zhenjiang,Jiangsu,212013 China [2]School of Material Science and Engineering,Nanyang Technological University,50 Nanyang Avenue,639798 Singapore [3]School of Energy and Power Engineering,Jiangsu University,301 Xuefu Road,Zhenjiang,Jiangsu,212013 China

出　　处：《Chinese Journal of Chemistry》2025年第1期61-66,共6页中国化学(英文版)

基　　金：supported by National Natural Science Foundation of China(52207238);China Postdoctoral Science Foundation(2023M731361);Jiangsu University Senior Talent Launch Fund.

摘　　要：Rapid dynamics and remarkable proton conduction induced by confined water in nanospaces have attracted much attentions from researchers,which is crucial for advancing the development of innovative proton conductors and deepening comprehension of proton and water transport mechanisms within biological systems.In this aspect,carbon nanotubes(CNTs)are frequently employed as a research platform.However,they possess certain limitations,such as their inherent electronic conductivity and extreme hydrophobicity,which can impede the accurate assessment and precise regulation of proton conduction.We herein prepared two 2D COFs with different hydrophilic fragment,and obtained maximum acid-free proton conductivity of 3.04×10^(–4) S·cm^(–1) at 70℃ and 100%RH with Grotthuss type activation energy of 0.14 eV.This is mainly due to that the water molecules in the center of channel form strong hydrogen bonds,enhancing proton dissociation and guiding fast directional diffusion.

关 键 词：Confined water Covalent organic frameworks Acid-free Proton conduction Hydrophilic fragment 

分 类 号：O57[理学—粒子物理与原子核物理]