高熵氧化物纳米材料在电化学储能领域的研究进展  

Research Progress on High-Entropy Oxide Nanomaterials in the Electrochemical Field

作　　者：陆敏萱 袁瑞梅 徐欣畅 张雪琳 魏葳 李贺军[2] LU Minxuan;YUAN Ruimei;XU Xinchang;ZHANG Xuelin;WEI Wei;LI Hejun(School ofTelecommunications Engineering,Xidian University,Xi'an 710071,China;State Key Laboratory of Solidification Processing,Northwestern Polytechnical University,Xi'an 710072,China;Academy of Advanced Interdisciplinary Research,Xidian University,Xi'an 710071,China;State Key Laboratory ofWide-Bandgap Semiconductor Devices and Integrated Technology,Xidian University,Xi'an 710071,China)

机构地区：[1]西安电子科技大学通信工程学院,陕西西安710071 [2]西北工业大学凝固技术国家重点实验室,陕西西安710072 [3]西安电子科技大学前沿交叉研究院,陕西西安710071 [4]西安电子科技大学宽禁带半导体器件与集成技术全国重点实验室,陕西西安710071

出　　处：《铸造技术》2025年第2期120-135,共16页Foundry Technology

基　　金：凝固技术国家重点实验室开放课题(SKLSP202317);陕西省自然科学基础研究计划(2024JC-YBQN-0571);陕西省重点研发计划(2018ZDXM-GY-142)。

摘　　要：高熵氧化物是由多种金属或非金属氧化物以等或近等比例固溶形成的单一结构氧化物,在电化学储能领域有着广泛的应用前景。本论文介绍了高熵氧化物现有优点(鸡尾酒效应、高熵效应、晶格畸变效应等)和合成方法,其主要包括高温固相反应法、热解法、共沉淀法、溶液燃烧合成法、水热合成法,以及基于其优异性能在催化制氢、超级电容器、锂电池等电化学储能领域的应用,综述了高熵氧化物在电化学储能领域的研究进展。A high-entropy oxide is a single structural oxide formed from a solid solution of a variety of metal or nonmetal oxides in equal or nearly equal proportions and has wide application prospects in the field of energy.This paper mainly introduces the advantages of high-entropy oxides(cocktail effects,high-entropy effects,lattice distortion effects,etc.)and synthesis methods,which mainly include the high-temperature solid-phase reaction method,pyrolysis method,coprecipitation method,solution combustion synthesis method,and hydrothermal synthesis method,and on the basis of their excellent performance in catalytic hydrogen production,supercapacitors,lithium batteries and other electrochemical energy storage applications.The research progress on high-entropy oxides in the field of electrochemical energy storage is reviewed.

关 键 词：高熵氧化物 电化学催化 电化学储能 

分 类 号：TB34[一般工业技术—材料科学与工程] TM912[电气工程—电力电子与电力传动]