基于FeCo_(2)O_(4)/g-C_(3)N_(4)/CA的光电协同去除小球藻影响因素研究  

Influencing Factors of Photo-electric Synergistic Removal of Chlorella vulgaris Based on FeCo_(2)O_(4)/g-C_(3)N_(4)/CA

作　　者：张甲 王晓波 赵文静 陈田田 田立平 李晓晨[1] 姜瑞雪[1] ZHANG Jia;WANG Xiao-bo;ZHAO Wen-jing;CHEN Tian-tian;TIAN Li-ping;LI Xiao-chen;JAING Rui-xue(China Water Conservancy and Civil Engineering College/Shandong Agricultural University,Tai'an 271018,China;Weifang municipal public utilities service center,Weifang 261041,China)

机构地区：[1]山东农业大学水利土木工程学院,山东泰安271018 [2]潍坊市市政公用事业服务中心,山东潍坊261041

出　　处：《山东农业大学学报(自然科学版)》2025年第1期110-118,共9页Journal of Shandong Agricultural University:Natural Science Edition

基　　金：光-电耦合氧化体系构建及灭藻效应机理研究(2022ZJ1095);宜居乡村供水安全保障及污染物协同资源化绿色低碳治理关键技术研发与示范(2023TZXD019);单过硫酸盐氧化体系中消毒副产物生成机制的研究(ZR2022QE215)。

摘　　要：有害藻华的频繁爆发会对水生态、水环境和人类健康构成严重威胁,传统的除藻技术存在一定的局限性,而光电协同催化是一种光催化和电氧化高效结合的新型技术,可弥补传统除藻技术的不足。本文以小球藻为模式生物,采用光电协同催化技术进行藻类去除试验。考察了FeCo_(2)O_(4)不同掺杂比、电流密度、电解质浓度、催化剂投加量和藻生物量对叶绿素a去除率的影响。结果表明:电流密度越高、电解质浓度越大、催化剂投加量越多和藻生物量越低时除藻效果最好。当电流密度为2.0 mA/cm^(2)、电解质浓度为0.10 M和催化剂投加量为0.30 g时,对藻生物量(6.0×10^(6)cells/mL)的去除率达到93.71%。因此,本研究可以为水体富营养化和藻类爆发的管理和控制提供科学依据。The frequent outbreaks of harmful algal blooms pose serious threats to aquatic ecosystems,water environments,and human health.Traditional algae removal technologies have certain limitations,whereas photo-electric synergistic,as a novel technology that efficiently combines photocatalysis with electrooxidation,can compensate for the deficiencies of traditional algae removal methods.We take Chlorella vulgaris as a model organism and uses photoelectric synergistic catalytic technology for algal removal experiments.We investigated the influence of different doping ratios of FeCo_(2)O_(4),current density,electrolyte concentration,catalyst dosage and algal biomass on the chlorophyll a removal rate.The results showed that the best algal removal effect was achieved at higher current density,higher electrolyte concentration,higher catalyst dosage and lower algal biomass.When the current density is 2.0 mA/cm^(2),the electrolyte concentration is 0.10 M,and the catalyst dosage is 0.30 g,the removal rate of algal biomass(6.0×10^(6)cells/mL)reaches 93.71%.Therefore,our study can provide scientific basis for the management and control of water eutrophication and algae outbreak.

关 键 词：光电协同 小球藻 叶绿素A 钴酸铁/石墨相氮化碳/醋酸纤维素 

分 类 号：X524[环境科学与工程—环境工程]