Lowering the kinetic barrier via enhancing electrophilicity of surface oxygen to boost acidic oxygen evolution reaction  

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作  者:Ling Tang Yan Wan Yangming Lin 

机构地区:[1]CAS Key Laboratory of Design and Assembly of Functional Nanostructures,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,350002,China [2]State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,350002,China [3]Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials,Xiamen Institute of Rare Earth Materials,Haixi Institute,Chinese Academy of Sciences,Xiamen,361021,China

出  处:《Chinese Journal of Structural Chemistry》2024年第11期4-5,共2页结构化学(英文)

基  金:support from the Xiamen City Natural Science Foundation of China(3502Z20227256);National Natural Science Foundation of China(22202205);Natural Science Foundation of Fujian Province(2022J01502).

摘  要:Oxygen evolution reaction(OER)is of significance in anodic reaction in the field of electrochemical energy conversion and storage,such as water splitting,metal-air battery,etc.[1,2].Being a thermodynamically downhill reaction comprising multiple-step proton coupled electron transfer within a narrow potential range(equations(1)-(5)),the reaction pathways involved in OER highly depend on the pH value of electrolyte[3,4].

关 键 词:NARROW ELECTROLYTE anodic 

分 类 号:O64[理学—物理化学]

 

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