Magnetic nanoparticle detection methods in the context of complex fluids  

作　　者：Alirza Orujov Jon M.Pikal TeYu Chien Jefferson A.Carter Saman A.Aryana 

机构地区：[1]Deptartment of Chemical and Biomedical Engineering,University of Wyoming,Laramie,WY,USA [2]Deptartment of Electrical Engineering and Computer Science,University of Wyoming,Laramie,WY,USA [3]Deptartment of Physics and Astronomy,University of Wyoming,Laramie,WY,USA

出　　处：《International Journal of Coal Science & Technology》2024年第6期173-184,共12页国际煤炭科学技术学报(英文)

基　　金：supported as part of the Center for Mechanistic Control of Unconventional Formations(CMC-UF),an Energy Frontier Research Center funded by the U.S.Department of Energy,Office of Science under DOE(BES)Award DE-SC0019165.

摘　　要：Foams improve mobility control in injection operations within geological settings.Nanoparticles,such as iron-oxide,have been shown to enhance the stability of foams when combined with surfactants.In this research,we leverage the magnetic properties of these nanoparticles to detect their presence as a surrogate for monitoring the geologic extent of injected fluids in the subsurface.The feasibility of using these nanoparticles for monitoring purposes stems from their detectability at low concentrations in subsurface environments.We developed two distinct methods to detect the presence of magnetite nanoparticles in complex fluids.To simulate complex subsurface fluids in a laboratory setting,we included various ions and surfactants and investigated their effects on the detection of nanoparticles.To this end,we designed an experimental setup and tested two magnetic detection methods:Induction Heating(IH)and Oscillator Frequency Shift(OFS).The IH method involves applying a high-frequency alternating magnetic field to a solution containing small amounts of magnetic nanoparticles and measuring the temperature response.We built an experimental setup to generate this magnetic field for different samples,with temperature changes recorded by an infrared camera.The results indicate that nanoparticle concentrations linearly affect the solution's temperature rise.However,the presence of ions and surfactants also influences the temperature response.The OFS method measures shifts in the resonance frequency of a circuit caused by changes in magnetic permeability inside a coil.This coil is part of a transistor oscillator circuit that produces a sinusoidal voltage waveform,with the oscillation frequency depending on the coil’s inductance.The presence of nanoparticles causes a shift in resonance frequency,which were precisely measured for various samples.The drop in resonance frequency is a linear function of nanoparticle concentration,and both methods detect concentrations as low as 150 mg/L of Fe_(3)O_(4)nanoparticles.

关 键 词：CO_(2) storage Monitoring Nanoparticle-stabilized foams SEQUESTRATION SUBSURFACE Tracer nanoparticles 

分 类 号：TB383[一般工业技术—材料科学与工程] O484.2[理学—固体物理]