Three-dimensional Ti_(3)C_(2)structure design and in-situ growth of nano-TiO_(2)crystals to realize high performance lithium-sulfur battery  

作　　者：Wenhao Yan Dan You Bingnan Deng Zhicong Ni Chunman Yang Fei Wang Yingjie Zhang Xue Li Yiyong Zhang Yunxiao Wang 

机构地区：[1]College of Metallurgical and Energy Engineering,Key Laboratory of Advanced Battery Materials of Yunnan Province,Kunming University of Science and Technology,Kunming 650093,China [2]Faculty of Materials Metallurgy and Chemistry,Jiangxi University of Science and Technology,Ganzhou 341000,China [3]Univ Wollongong,Australian Inst Innovat Mat,Inst Superconducting&Elect Mat,Innovat Campus,Squires Way,Wollongong,NSW 2500,Australia

出　　处：《Journal of Materials Science & Technology》2024年第26期187-198,共12页材料科学技术(英文版)

基　　金：the Natural Science Foundation of Yunnan Province(Grant Nos.202001AU070079,21965017,202101AW070006).

摘　　要：Lithium-sulfur(Li-S)batteries represent a promising energy storage system with the potential to replace traditional lithium-ion batteries.Recent research has explored the practical applications of Li-S batteries.However,due to the insulation properties of the sulfur components and the shuttle effect of polysulfides,the practical application of Li-S batteries is hindered by poor cycle stability and short life.In this study,we developed a controllable three-dimensional Ti_(3)C_(2)structure design process,and through in situ growth of TiO_(2)nanocrystals,we prepared three-dimensional porous materials with TiO_(2)@Ti_(3)C_(2)heterostructures.These materials constructed using two-dimensional lamellar Ti_(3)C_(2)function as a conductive skeleton to improve the conductivity of the sulfur cathodes,and through the in-situ growth of nano-TiO_(2)to introduce more binding sites and provide more chemisorption sites to limit the dissolution and shuttle of polysulfides.In addition,the TiO_(2)@Ti_(3)C_(2)heterointerface generated in situ on the surface of the lamellar structure can induce an internal electric field and increase active reaction sites,which promotes reaction kinetics,accelerates charge diffusion/transport,and promotes LiPS transformation.The materials designed in this study can effectively restrain the shuttle effect by realising the association process of adsorption,capture,and transformation of polysulfides.Thus,when applied as the sulfur cathode frame,it shows a high specific capacity of 1261.41 mAh g^(-1)at a rate of 0.1 C.In addition,a specific capacity of 66.5%is maintained over 500 cycles at a rate of 1 C.This strategy supports the development of Li-S batteries with extraordinary performance and opens up a promising way to design next-generation electrochemical energy storage devices.

关 键 词：Ti_(3)C_(2) TiO_(2) Multifunctional synergy Heterogeneous interface Lithium-sulfur battery 

分 类 号：TM9[电气工程—电力电子与电力传动]