Engineering the conjugation of donor and acceptor units in covalent organic frameworks for efficient photocatalytic H_(2)O_(2)synthesis  

共价有机框架供体-受体单元共轭工程学用于高效光催化合成双氧水

作　　者：Xu Ding Tianying Wang Qianjun Zhi Tianyu Zheng Yucheng Jin Heyuan Liu Hailong Wang Dongdong Qi Pavel A.Stuzhin Jianzhuang Jiang 丁旭;王恬英;智倩君;郑天宇;金昱丞;刘和元;王海龙;齐冬冬;Pavel A.Stuzhin;姜建壮

机构地区：[1]Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials,Department of Chemistry and Chemical Engineering,School of Chemistry and Biological Engineering,University of Science and Technology Beijing,Beijing 100083,China [2]School of Materials Science and Engineering,China University of Petroleum(East China),Qingdao 266580,China [3]Research Institute of Macroheterocycles,Ivanovo State University of Chemistry&Technology,Ivanovo,153000,Russia

出　　处：《Science Bulletin》2025年第4期464-468,共5页科学通报(英文版)

基　　金：supported by the National Natural Science Foundation of China(22235001,22175020,22131005,and 22261132512);Xiaomi Young Scholar Program,Fundamental Research Funds for the Central Universities(FRF-EYIT-23-02 and QNXM2023);the University of Science and Technology Beijing,and the Russian Science Foundation within the framework of the Joint RSF-NSFC project(23-43-00136).

摘　　要：The boom of covalent organic frameworks(COFs)has been witnessed in the photocatalysis field in recent years owing to the capability of these materials to efficiently and sustainably harness solar energy[1],[2].Prepared from diverse aromatic building blocks,COFs have well-defined periodic structures and uniform porosities,allowing for the adjustment of photocatalytic activity at precise atomic and molecular levels.

关 键 词：DONOR PHOTOCATALYTIC SYNTHESIS 

分 类 号：O62[理学—有机化学]