Solid-electrolyte interphases for all-solid-state batteries  

作　　者：Yu Xia Xu Han Yue Ji Simeng Zhang Saiqi Wei Yue Gong Junyi Yue Yueyue Wang Xiaona Li Zhiqiang Fang Changtai Zhao Jianwen Liang 

机构地区：[1]National Power Battery Innovation Center,GRINM Group Co.,Ltd.,Beijing 100088,China [2]Solid State Batteries Research Center,GRINM(Guangdong)Institute for Advanced Materials and Technology,Foshan 528051,China [3]China Automotive Battery Research Institute Co.,Ltd.,Beijing 100088,China [4]General Research Institute for Nonferrous Metals,Beijing 100088,China [5]Eastern Institute for Advanced Study,Eastern Institute of Technology,Ningbo 315200,China [6]School of Materials Science and Engineering,University of Science and Technology Beijing,Beijing 100083,China [7]Key Laboratory of Automobile Materials of Ministry of Education&School of Materials Science and Engineering,Nanling Campus,Jilin University,Changchun 130025,China [8]China FAW Corporation Limited,Changchun 130013,China

出　　处：《ChemPhysMater》2025年第1期9-29,共21页化学物理材料(英文)

基　　金：This research was supported by the National Key R&D Program of China(2022YFB3506300);National Natural Science Foundation of China(No.52176185);Guangdong-Foshan Joint Fund(2023A1515140091);Guangdong High-level Innovation Institute project(2021B090905000);Ningbo Yongjiang Talent Introduction Program(2023A-184-G)Eastern Institute of Technology,Ningbo.

摘　　要：Interfacial engineering,particularly the design of artificial solid-electrolyte interphases(SEIs),has been successfully applied in all-solid-state batteries(ASSLBs)for industrial applications.However,a fundamental understanding of the synthesis and mechanism models of artificial SEIs in all-solid-state Li-ion batteries remains limited.In this review,recent advances in designing and synthesizing artificial SEIs for ASSLBs to solve interfacial issues are thoroughly discussed,covering three main preparation methods and their technical routes:1)atomic layer deposition,2)sol-gel methods,and 3)mechanical ball-milling methods.Moreover,advanced ex-situ characterization techniques for artificial SEIs are comprehensively summarized.Finally,this review provides perspectives on techniques for the interface engineering of artificial SEIs for ASSLBs,with focus on promising methods for industrial applications.

关 键 词：All-solid-state lithium batteries Interfacial engineering Solid-electrolyte interphase Atomic layer deposition Sol-gel Mechanical ball-milling 

分 类 号：TM9[电气工程—电力电子与电力传动]