Perovskite Oxides Toward Oxygen Evolution Reaction:Intellectual Design Strategies,Properties and Perspectives  

作　　者：Lin-Bo Liu Chenxing Yi Hong-Cheng Mi Song Lin Zhang Xian-Zhu Fu Jing-Li Luo Subiao Liu 

机构地区：[1]School of Minerals Processing and Bioengineering,Central South University,Changsha 410083,Hunan,China [2]Institute of Materials Research and Engineering,Agency for Science,Technology and Research,2 Fusionopolis Way,Innovis,#08-03,Singapore 138634,Singapore [3]College of Materials Science and Engineering,Shenzhen University,Shenzhen 518000,China [4]Department of Chemical and Materials Engineering,University of Alberta,Edmonton,AB T6G 1H9,Canada

出　　处：《Electrochemical Energy Reviews》2024年第1期447-483,共37页电化学能源评论(英文)

基　　金：supported by the National Natural Science Foundation of China(NSFC,Grant No.22109182);the Natural Science Foundation of Hunan Province,China(2022JJ30684);the Start-up Funding of Central South University(No.206030104);the Natural Sciences and Engineering Research Council(NSERC)of Canada Discovery Grant(GRPIN−2016−05494).

摘　　要：Developing electrochemical energy storage and conversion devices(e.g.,water splitting,regenerative fuel cells and rechargeable metal-air batteries)driven by intermittent renewable energy sources holds a great potential to facilitate global energy transition and alleviate the associated environmental issues.However,the involved kinetically sluggish oxygen evolution reaction(OER)severely limits the entire reaction efficiency,thus designing high-performance materials toward efficient OER is of prime significance to remove this obstacle.Among various materials,cost-effective perovskite oxides have drawn particular attention due to their desirable catalytic activity,excellent stability and large reserves.To date,substantial efforts have been dedicated with varying degrees of success to promoting OER on perovskite oxides,which have generated multiple reviews from various perspectives,e.g.,electronic structure modulation and heteroatom doping and various applications.Nonetheless,the reviews that comprehensively and systematically focus on the latest intellectual design strategies of perovskite oxides toward efficient OER are quite limited.To bridge the gap,this review thus emphatically concentrates on this very topic with broader coverages,more comparative discussions and deeper insights into the synthetic modulation,doping,surface engineering,structure mutation and hybrids.More specifically,this review elucidates,in details,the underlying causality between the being-tuned physiochemical properties[e.g.,electronic structure,metal-oxygen(M-O)bonding configuration,adsorption capacity of oxygenated species and electrical conductivity]of the intellectually designed perovskite oxides and the resulting OER performances,coupled with perspectives and potential challenges on future research.It is our sincere hope for this review to provide the scientific community with more insights for developing advanced perovskite oxides with high OER catalytic efficiency and further stimulate more exciting applications.

关 键 词：Perovskite oxides Oxygen evolution reaction Synthetic modulation DOPING Surface engineering Structure mutation HYBRIDS 

分 类 号：O64[理学—物理化学]