典型热化学反应器技术的发展历程  

Progress History of Typical Thermochemical Reactor Technology

作　　者：宋兴飞 刘宇涧 贾鑫 安萍 韩振南 程继光 许光文 SONG Xingfei;LIU Yujian;JIA Xin;AN Ping;HAN Zhennan;CHENG Jiguang;XU Guangwen(Key Laboratory on Resources Chemicals and Materials of Ministry of Education,Shenyang University of Chemical Technology,Shenyang 110142,China)

机构地区：[1]特色资源化工与材料教育部重点实验室,沈阳化工大学,辽宁沈阳110142

出　　处：《化学反应工程与工艺》2025年第1期33-43,共11页Chemical Reaction Engineering and Technology

基　　金：国家自然科学基金(22242018);2024年度辽宁省科协科技创新智库项目(LNKX2024BG02)。

摘　　要：热化学反应工程是研究以“热”诱发或“热”驱动的化学反应的工程科学与技术,与光化学反应工程、电化学反应工程、催化反应工程、聚合反应工程等同属于化学反应工程的重要分支,也是“工程热化学”新兴交叉学科的关键基础。热化学反应工程广泛应用于化工、能源、冶金、材料、环境、航空航天和国防等众多工业领域,其核心设备为热化学反应器,反应器内部的动量、质量和热量的传递过程直接影响着工艺效率与产品质量。本文聚焦热化学反应工业中具有代表性的五个行业:气化、热解、钢铁、炭黑和水泥,系统梳理了典型热化学反应器的发展历程,重点分析了原料种类、反应器形式、供热方式及反应类型等关键要素的演变。通过揭示“热”与“反应”在微观尺度、反应器尺度以及过程/系统尺度上的匹配机制,探讨了其对各行业技术进步的推动作用,为热化学反应工程领域的快速、低碳、创新发展提供可借鉴的思路和参考。Thermochemical reaction engineering is the research on the science and technology of thermochemical reactions which are induced or driven by heat.Alongside photochemical reaction engineering,electrochemical reaction engineering,catalytic reaction engineering,and polymer reaction engineering,it is a major branch of chemical reaction engineering and serves as a fundamental pillar of the interdisciplinary field of"engineering thermochemistry."Thermochemical reaction engineering finds broad applications in industries such as chemicals,energy,metallurgy,materials,environment,aerospace,and defense,with the core equipment is the thermochemical reactor.The transfer processes of momentum,mass,and heat within the reactor directly impact the efficiency of the process and the quality of the products.This study introduced five businesses that were indicative of the thermochemical reaction sector:cement manufacturing,steelmaking,carbon black production,gasification,and pyrolysis.With an emphasis on the development of crucial components such feedstock types,reactor layouts,heating techniques,and reaction mechanisms,it methodically examined the evolution of common thermochemical reactors.The study investigated how"heat"and"reaction"match at the micro,reactor,and process/system scales and how these influenced technical progress in these sectors.The results were intended to offer useful information and sources for the quick,low-carbon,and creative advancement of thermochemical reaction engineering.

关 键 词：热化学反应 热化学反应工程 反应器 

分 类 号：T09[一般工业技术]