氮掺杂生物质炭的制备及作为催化剂载体在加氢领域研究进展  

Research progress on preparation of nitrogen-doped carbon materials from biomass and its application as catalyst carrier in hydrogenation field

作　　者：赵文强 邹胜[1] 白元盛[1,2] 王庆印 王自庆[3] 王昊君 王公应 ZHAO Wenqiang;ZOU Sheng;BAI Yuansheng;WANG Qingyin;WANG Ziqing;WANG Haojun;WANG Gongying(Chengdu Organic Chemistry Co.,Ltd.,Chinese Academy of Sciences,Chengdu 610041,Sichuan,China;University of Chinese Academy of Sciences,Beijing 100049,China;School of Chemistry and Chemical Engineering,Shihezi University,Shihezi 832003,Xinjiang,China;Xinjiang Blue Ridge Tunhe Sci.&Tech.Co.,Ltd.,Changji 831100,Xinjiang,China)

机构地区：[1]中国科学院成都有机化学有限公司,四川成都610041 [2]中国科学院大学,北京100049 [3]石河子大学化学化工学院,新疆石河子832003 [4]新疆蓝山屯河聚酯有限公司,新疆昌吉831100

出　　处：《低碳化学与化工》2025年第3期71-81,共11页Low-Carbon Chemistry and Chemical Engineering

基　　金：中央在川高校院所重大科技成果转化项目(2022ZHCG0135);丝绸之路经济带创新驱动发展试验区、乌昌石国家自主创新示范区科技发展计划项目(2023112258)。

摘　　要：为实现“双碳”目标,高效催化低碳化合物加氢实现其高价值利用以及将来源广泛、可再生的生物质作为原料制备氮掺杂生物质炭材料用于催化加氢反应是当前研究热点。然而生物质的复杂性导致其在制备氮掺杂生物质炭材料时,炭材料表面性质与结构特性存在较大差异,氮掺杂生物质炭材料在催化加氢领域的工业应用仍存在较大挑战。对氮掺杂生物质炭材料制备及其作为催化剂载体在加氢领域的研究进行了综述。首先阐述了氮掺杂物种的类型及性质、氮掺杂生物质炭材料典型制备方法;其次,与其他催化剂载体进行了对比,总结了近年来国内外氮掺杂生物质炭材料在催化加氢反应中的研究进展;最后,对用于催化加氢领域的氮掺杂生物质炭材料的未来发展趋势进行了展望,以期为推动氮掺杂生物质炭材料在催化加氢领域的发展提供参考。In order to achieve“carbon peaking and carbon neutrality goals”,the efficient catalytic hydrogenation of low-carbon compounds to realize their high-value utilization and the preparation of nitrogen-doped carbon materials from biomass,which is widely available and renewable,as a feedstock for the catalytic hydrogenation reaction are the hot spots of current research.However,the complexity of biomass leads to the large differences in the surface properties and structural characteristics of carbon materials when preparing nitrogen-doped biochar,and the industrial application of nitrogen-doped biomass carbon materials in the field of catalytic hydrogenation is still a big challenge.The research on the preparation of nitrogen-doped biomass carbon materials and their use as catalyst carriers in hydrogenation was reviewed.Firstly,the types and properties of nitrogen-doped species and the typical preparation methods of nitrogen-doped biomass carbon materials were described.Secondly,the research progress on nitrogen-doped biomass carbon materials in catalytic hydrogenation reactions at home and abroad in recent years was summarized by comparing them with other catalyst carriers.Finally,the future development trends of nitrogen-doped biomass carbon materials used in the field of catalytic hydrogenation were prospected,with the aim of providing references for promoting the progress on nitrogen-doped biomass carbon materials in the field of catalytic hydrogenation.

关 键 词：生物质 氮掺杂 炭材料 催化剂载体 催化剂 加氢 

分 类 号：TQ426[化学工程] O643.3[理学—物理化学]