Porous organic framework materials for photocatalytic H2O2 production  

作　　者：Yepeng Yang Chengjiao Wang Yizhou Li Kong Liu Haidong Ju Jiaqiang Wang Rao Tao 

机构地区：[1]Yunnan Engineering Technology Research Center for Plastic Films,Yunnan Key Laboratory of Metal-Organic Molecular Materials and Device,School of Chemistry and Chemical Engineering,Kunming University,Kunming 650214,China [2]School of Chemical Sciences&Technology,National Center for International Research on Photoelectric and Energy Materials,Yunnan Province Engineering Research Center of Photocatalytic Treatment of Industrial Wastewater,School of Materials and Energy,Yunnan University,Kunming 650091,China

出　　处：《Journal of Materials Science & Technology》2024年第33期185-214,共30页材料科学技术(英文版)

基　　金：supported by the Yunnan Fundamental Re-search Project(No.202301AU070037);the Education Depart-ment Project of Yunnan Province(No.2023J0837);the Talent Introduction Project of Kunming University(Nos.YJL23018 and YJL23019);the Cooperative Research Program of Yunnan Provincial Undergraduate Universities’Association(No.202301BA070001-128);the National Natural Science Foundation of China(Nos.22062026 and22165016);the Industrialization Cultivation Project(No.2016CYH04);the Yunling Scholar(No.YNWR-YLXZ-2019-002);the Reserve Talents of Young and Middle-aged Academic and Tech-nical Leaders in Yunnan Province(No.202205AC160042)。

摘　　要：Hydrogen peroxide(H_(2)O_(2))has been recognized as a rather important chemical with extensive applications in environmental protection,chemical synthesis,military manufacturing,etc.However,the mature industrial strategy(i.e.,anthraquinone oxidation)for H_(2)O_(2)production is featured with heavy pollution and high energy consumption.Photocatalytic technology has been regarded as a sustainable strategy to convert H_(2)O and O_(2)into H_(2)O_(2).Recently,porous organic framework materials(POFs)including metalorganic frameworks(MOFs),covalent organic frameworks(COFs),covalent triazine frameworks(CTFs),covalent heptazine frameworks(CHFs),and hydrogen-bonded organic frameworks(HOFs)have exhibited significant potential for green H_(2)O_(2)photosynthesis by virtue of their diverse synthesis methods,enormous specific surface areas,flexible design,adjustable band structure,and photoelectric property.In this review,the recent advances in H_(2)O_(2)photosynthesis based on POFs are comprehensively investigated.The modification strategies to improve H_(2)O_(2)production and their photocatalytic mechanisms are systematically analyzed.The current challenges and future perspectives in this field are highlighted as well.This review aims to give a complete picture of the research effort made to provide a deep understanding of the structure-activity relationship of H_(2)O_(2)photogeneration over POFs,thus inspiring some new ideas to tackle the challenges in this field,and finally stimulating the efficient development of organic semiconductors for sustainable photogeneration of H_(2)O_(2).

关 键 词：Porous organic frameworks(POFs) Hydrogen peroxide(H_(2)O_(2)) PHOTOCATALYSIS Metal organic frameworks(MOFs) Covalent organic frameworks(COFs) 

分 类 号：F42[经济管理—产业经济]