聚醚多元醇型聚丁二酸丁二醇的合成与性能研究  

Study on the Synthesis and Properties of Polyether Polyol Type Polybutylene Succinate

作　　者：黄继涛[1] 余洲 徐艺贞 蔡诗琪 张夜 李耀斌 Huang Jitao;Yu Zhou;Xu Yizhen;Cai Shiqi;Zhang Ye;Li Yaobin(College of Chemistry and Materials,Ningde Normal University,Ningde 352100,China)

机构地区：[1]宁德师范学院新能源与材料学院,福建宁德352100

出　　处：《广东化工》2025年第4期1-3,42,共4页Guangdong Chemical Industry

基　　金：福建省教育厅中青年基金项目(2020Q104);福建省大学生创新创业项目(S202210398028)。

摘　　要：本实验采用熔融缩聚法制备聚丁二酸丁二醇酯(PBS)。利用聚醚多元醇具有分子高度旋转性的特点,对PBS进行化学改性,合成了聚醚多元醇型PBS。通过X射线衍射仪(XRD)、傅立叶红外变换光谱仪(FTIR)、热失重分析仪(TG)、差示扫描量热仪(DSC)和特性黏度测试手段对实验产物进行结构表征以及性能分析。结果表明:成功合成了具有较高分子量的聚醚多元醇型PBS;改性后PBS热稳定性升高,柔韧性好,更有利于加工制造。In this paper,polybutylene succinate(PBS)was prepared by melt polycondensation method.Utilizing the high molecular rotation offered by polyether polyols,PBS was chemically modified to synthesize polyether polyol-modified PBS.The structural and functional attributes of the experimental product were characterized employing X-ray diffraction(XRD),Fourier transform infrared spectroscopy(FTIR),thermogravimetric analysis(TG),differential scanning calorimetry(DSC),and intrinsic viscosity testing methods.The results indicated that a high molecular weight polyether polyol-modified PBS was successfully synthesized.Following modification,the thermal stability of PBS was enhanced,exhibiting improved flexibility,which is more conducive to processing and production.

关 键 词：聚丁二酸丁二醇酯 熔融缩聚 聚醚多元醇 改性 

分 类 号：TQ[化学工程]