呋喃查尔酮丙烯酸锌主链防污树脂/涂层的制备及其性能研究  

Preparation of Antifouling Resins/Coatings with Zinc Furanchalcone Acrylate Backbone and Study of Their Properties

作　　者：张习汝 张海春 范会生 孙保库 陆阿定 ZHANG Xi-ru;ZHANG Hai-chun;FAN Hui-sheng;SUN Bao-ku;LU A-ding(Department of Marine Environment and Chemical Engineering,Zhejiang Institute of Ocean Development,Zhoushan 316000,Zhejiang,China)

机构地区：[1]浙江省海洋开发研究院海洋环境与化工研究室,浙江舟山316000

出　　处：《中国涂料》2025年第1期26-31,共6页China Coatings

基　　金：呋喃查尔酮丙烯酸锌主链防污树脂的制备及其性能研究(2022C61005);丙烯酸锌防污涂料中试关键技术与应用研究(2022C61006)。

摘　　要：设计了一种可以提升树脂材料本身防污性能的分子策略。在均质条件下利用克莱森–施密特缩合法合成环境友好且具有防污活性的呋喃查尔酮(FC)。FC与丙烯酸酯通过聚合反应制备出具有防污活性的水解防污树脂。再将经FC改性的防污树脂配成涂料进行海洋挂板实验。结果表明,含有此种防污因子的丙烯酸酯树脂的涂料表现出优异的防污性能。This study devised a molecular strategy aimed at augmenting the antifouling capabilities of resin materials intrinsically.Environmentally friendly and antifouling-active furan-based chalcone(FC) was synthesized under homogeneous conditions via the Claisen-Schmidt condensation method.Hydrolyzed resins with antifouling activity were fabricated through the polymerization of FC with acrylates.The FC-modified antifouling resin was then formulated into coatings for marine wallboard experiments.The findings demonstrated that the coatings incorporating this antifouling factor within the acrylic resin displayed outstanding antifouling performance.

关 键 词：抗菌 自抛光 树脂 涂层 自由基聚合 

分 类 号：TQ630.4[化学工程—精细化工]