聚氨酯共聚硅氧烷在织物风格整理中的应用  

Application of Polyurethane Copolysiloxane in Fabric Style Finishing

作　　者：张必洋 夏虎 倪丽杰 胡同坤[3,5] Zhang Biyang;Xia Hu;Ni Lije;Hu Tongkun(Faculty of Textile Science&Engineering,Wuhan Textile University,Wuhan,Hubei 430200,China;Zhejiang Provincial Key Laboratory of Clean Dyeing and Finishing Technology Research(Shaoxing University),Shaoxing,Zhejiang 312000,China;Postgraduate Workstation of Wuhan Textile University(Hubei Daya),Wuhan,Hubei 430200,China;Faculty of Chemistry&Chemical Engineering,Wuhan Textile University,Wuhan,Hubei 430200,China;Hubei Daya Biotechnology Co.,Ltd.,Jingzhou,Hubei 434200,China)

机构地区：[1]武汉纺织大学纺织科学与工程学院,湖北武汉430200 [2]浙江省清洁染整技术研究重点实验室(绍兴文理学院),浙江绍兴312000 [3]武汉纺织大学(湖北达雅)研究生工作站,湖北武汉430200 [4]武汉纺织大学化学与化工学院,湖北武汉430200 [5]湖北达雅生物科技股份有限公司,湖北荆州434200

出　　处：《针织工业》2025年第3期36-40,共5页Knitting Industries

基　　金：湖北省科技厅科技计划项目(2023BAB125);浙江省清洁染整技术研究重点实验室开放基金资助(QJRZ2210);2024荆州市科技计划项目(2024AA12);武汉纺织大学校基金(B)(K24081)。

摘　　要：分别以自制3种结构(支化型、网络微交联型、链式行星型)的非离子聚氨酯共聚硅氧烷NPU-Si系列和阳离子聚氨酯共聚硅氧烷CPU-Si系列共6支纺织品风格整理剂,与市售氨基硅油(AJ)复配后对织物进行整理,并分析织物表面元素分布、折皱回复角、亲水性、抗静电性和综合手感。结果表明:NPU-Si系列能有效提高织物的亲水性、抗静电性和弹性;CPU-Si系列产物中,经CPU-Si-B(阳离子支化型)整理后的织物抗皱性最好,经纬向折皱回复角由原布的107.2°提高至190.0°。NPU-Si与CPU-Si系列产物均能提升织物的柔软感、顺滑度和蓬松度。A total of six textile style finishing agents were prepared with three types of structures(branched,network micro-crosslinked and link chain softener)of nonionic polyurethane copolymer silicone NPU-Si and cationic polyurethane copolymer silicone CPU-Si,respectively,or compounded with commercially available amino silicone oil(AJ)for fabric.The surface element distribution,crease recovery angle,hydrophilicity,antistatic property and overall hand-feelof the fabrics were analyzed.The results show that NPU-Si series can effectively improve the hydrophilicity,antistatic property and elasticity of the fabric.Among the CPU-Si series products,the fabric after CPU-Si-B(cation support type)has the best wrinkle resistance,and the wrinkle relief angle increases from 107.2°of the original cloth to 190.0°.NPU-Si and CPU-Si series products can improve the softness,smoothness and fluffiness of fabrics.

关 键 词：聚氨酯共聚硅氧烷 亲水 高弹 抗静电 手感 

分 类 号：TS195.5[轻工技术与工程—纺织化学与染整工程]