阻燃硅树脂的研究进展  

Research Progress of Flame-Retardant Silicone Resin

作　　者：沈琪力 李智楷 杨小龙 刘珠 强娜 林熔 胡嘉欣 方岩雄[1,3] SHEN Qili;LI Zhikai;YANG Xiaolong;LIU Zhu;QIANG Na;LIN Rong;HU Jiaxin;FANG Yanxiong(Faculty of Chemical Engineering and Light Industry,Guangdong University of Technology,Guangzhou 510006,China;Guangdong Provincial Education Department Development Team of Advanced Material Coating and Surface Interface Technology,Huizhou Engineering Technology Research Center of Advanced Coating Materials,Dayawan Chemical Engineering Research Institute of Huizhou University,School of Dayawan Chemical and New Materials,School of Chemistry and Materials Engineering,Huizhou University,Huizhou 516007,China;Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory,Jieyang 522000,China)

机构地区：[1]广东工业大学轻工化工学院,广州516006 [2]惠州学院大亚湾化工新材料学院,惠州学院大亚湾化工研究院,惠州学院化学与材料工程学院,广东省教育厅先进材料涂层与表界面技术开发团队,惠州市先进涂层材料工程技术研究中心,广东惠州516007 [3]化学与精细化工广东省实验室揭阳分中心,广东揭阳515200

出　　处：《有机硅材料》2025年第2期58-64,共7页Silicone Material

基　　金：广东省重点建设学科科研能力提升项目(2021ZDJS081,2022ZDJS053,2022ZDJS054);广东省普通高校重点科研平台项目《包装印刷新型材料创新团队》(2022KCXTD035);广东省科技创新战略专项资金(“攀登计划”专项资金)(pdjh2022b0502,pdjh2023b0502);大学生创新创业训练计划项目(S202310577115X,CX2023014,CX2023031,CY2024161,S202410577115X,S202410577047);惠州学院教学质量与教学改革工程建设项目(惠院发〔2022〕163号,序号:26和27号;惠院发〔2023〕序号:150和149号);广东省“百千万工程”农村科技特派员项目(KTP20240327)。

摘　　要：硅树脂独特的半有机半无机特性,使其不仅具有优异的耐高低温、抗老化及抗氧化性,而且可在不影响其加工性和机械性能的情况下,提升高分子材料的热稳定性和阻燃性。同时硅树脂在燃烧过程中能够显著减少卤化氢等有害气体的释放,是一种高效、无卤且环保的阻燃材料,因此受到了阻燃领域的广泛关注。本文综述了硅树脂的热稳定性机理,并对阻燃硅树脂进行了分类总结,阐述了当前阻燃硅树脂的研究进展及复合阻燃硅树脂体系之间的协同效应,详细综述了各类阻燃硅树脂的研究状况和发展趋势,最后展望了阻燃硅树脂的发展方向。Due to its unique semi-organic and semi-inorganic characteristics,silicone resin not only exhibits excellent high and low temperature resistance,anti-aging and oxidation resistance,but also can strengthen the thermal stability and flame retardant of polymers without compromising its processability and mechanical properties.During combustion,silicone resin can significantly reduce the release of harmful gases,such as hydrogen halides,making it an efficient,halogen-free,and environmentally friendly flame retardant materials.Thus it has attracted widespread attention in the field of flame retardancy.This paper reviews the thermal stability mechanism of silicone resin,classifies and summarizes the flame retardant silicone resin,discusses the syn ergistic effects within composite flame retardant silicone resin,provides a detailed research and development trends of various flame retardant silicone resin,and looks forward to the development of flame retardant silicone resin.

关 键 词：硅树脂 阻燃 热稳定性 无卤环保 

分 类 号：TQ324.21[化学工程—合成树脂塑料工业]