气相色谱质谱法测定地表水中7种甲氧基丙烯酸酯类杀菌剂  

Determination of seven methoxyacrylate fungicides in surface water by GC-MS

作　　者：王刚锋 刘怡昕 WANG Gang-feng;LIU Yi-xin(Two/Three Institute of Nuclear Industry,Xi′an 710086,China;School of Pharmacy,Tianjin Medical University,Tianjin 300070,China)

机构地区：[1]核工业二0三研究所,陕西西安710086 [2]天津医科大学药学院,天津300070

出　　处：《化学工程师》2025年第3期36-38,104,共4页Chemical Engineer

摘　　要：建立了小体积液液萃取-气相色谱质谱法测定地表水中7种甲氧基丙烯酸酯类杀菌剂。7种甲氧基丙烯酸酯类杀菌剂在5.00~400μg·L^(-1)浓度范围内具有良好的线性关系,相关系数均大于0.995,检出限为0.04~0.13μg·L^(-1),3种加标浓度水平下的加标回收率为87.7%~104.0%,测定结果的相对标准偏差均不大于5%(n=6)。本方法操作简便,所需有机试剂较少,测试灵敏度高,结果准确可靠,能够满足地表水中啶氧菌酯、嘧螨酯、肟菌酯等甲氧基丙烯酸酯类杀菌剂的测定。A method for the determination of 7 methoxyacrylate fungicides in surface water by liquid extraction with gas chromatography-mass spectrometry was established.The seven methoxyacrylate fungicides had a good linear relationship in the concentration range of 5.00~400μg·L^(-1),and the correlation coefficients were all greater than 0.995.The detection limits were 0.04~0.13μg·L^(-1),and the recoveries were 87.7%~104.0%.The relative standard deviation of the measured results was less than 5%(n=6).The method is simple to operate,requires less organic reagents,has high sensitivity,accuracy and reliability,and can meet the requirements for the determination of methoxyacrylate fungicides in surface water,such as ridoxyl ester,pyrimidin ester and oxime ester.

关 键 词：小体积液液萃取 气相色谱质谱法 地表水 甲氧基丙烯酸酯类杀菌剂 

分 类 号：X832[环境科学与工程—环境工程]