Eco-friendly nano-enabled fertilizers derived from date industry waste for sustainable and controlled-release of P,K and Mg nutrients:sorption mechanisms,controlled-release performance and kinetics  

作　　者：Samira S.Elsabagh Elsayed A.Elkhatib Mohamed Rashad 

机构地区：[1]Arid Lands Cultivation Research Institute,City of Scientific Research and Technological Applications,New Borg El-Arab,Alexandria 21934,Egypt [2]Department of Soil and Water Sciences,Faculty of Agriculture(El-Shatby),Alexandria University,Alexandria 21545,Egypt.

出　　处：《Bioresources and Bioprocessing》2024年第1期28-42,共15页生物资源与生物加工(英文)

基　　金：Open access funding provided by The Science,Technology&Innovation Funding Authority(STDF)in cooperation with The Egyptian Knowledge Bank(EKB);Open access funding is provided by Science,Technology&Innovation Funding Authority(STDF)in cooperation with Egyptian Knowledge Bank(EKB)(Springer Nature OA agreements for Egypt).

摘　　要：Development of nano-enabled fertilizers from green waste is one of the effective options to enhance global agricultural productions and minimize environmental pollution.In this study,novel,eco-friendly and cost-effective nano-enabled fertilizers(NEF)were synthesized using the planetary ball milling procedure.The NEF(nDPF1and nDPF2)were prepared by impregnation of nanostructured date palm pits(nDPP)with(KH2PO4+MgO)at 1:1 and 3:1(w/w)ratios respectively.The nDPP,nDPF1 and nDPF2 were extensively characterized.The produced nano-fertilizers enhanced soil water retention capacity with nDPF2 being the most effective.The water retention capacity of nDPF2 treated soil was 5.6 times higher than that of soil treated with conventional fertilizers.In addition,the nDPF2 exhibited superior sustained lower release rates of P,K and Mg nutrients for longer release periods in comparison with the conventional fertilizers.For instance,P cumulative release percentages from conventional fertilizers,nDPF1 and nDPF2 in soil reached 22.41%,10.82 and 8.9%respectively within 384 h.Findings from FTIR and XPS analyses suggested that hydrogen bonding and ligand exchange were the main interaction mechanisms of PO4-K-Mg ions with nDPP surface.The released kinetics data of the NEF revealed that power function was the best suitable model to describe the kinetics of P,K and Mg release data from NEF in water and soil.Pot study ascertained that the nano-enabled fertilizers(nDPF1 and nDPF2)significantly promoted biomass production and nutrient uptake of maize plants as compared to commercial fertilizer treated plants.The present work demonstrated the potential of NEF to increase nutrients uptake efficiency,mitigate moisture retention problem in arid soils and reduce nutrients loss through leaching and safeguard the environment.

关 键 词：Date palm pits Water retention Mechanisms of nutrients adsorption Controlled release Sustainable agriculture Nano-carrier Green byproducts 

分 类 号：S15[农业科学—土壤学]