Strategies for molecular construction and performance regulation of heat-resistant energetic materials:An overview  

作　　者：Jing Zhang Bojun Tan Qian Zhang Shaoli Chen Yongxing Tang Ning Liu 

机构地区：[1]Xi'an Modern Chemistry Research Institute,Xi'an,710065,China [2]School of Astronautics,Northwestern Polytechnical University,Xi'an,710129,China [3]School of Chemistry and Chemical Engineering,Nanjing University of Science and Technology,Nanjing,210094,China [4]State Key Laboratory of Fluorine & Nitrogen Chemicals,Xi'an,710065,China

出　　处：《Progress in Natural Science:Materials International》2024年第6期1132-1157,共26页自然科学进展·国际材料(英文版)

基　　金：supported by the National Natural Science Foundation of China (22105156 and 22175139)

摘　　要：With the rapid development of deep-well blasting,aerospace and other fields,heat-resistant energetic materials have attracted wide attention of scientists all over the world.In this paper,the latest research progress of heatresistant energetic materials based on benzene ring,bridged nitrogen heterocyclic ring,coupled nitrogen heterocyclic ring,fused nitrogen heterocyclic ring,molecular perovskite and energetic metal-organic framework is reviewed.The review delves into the synthetic routes,physical and chemical properties of these diverse materials,facilitating a comparative analysis to deepen understanding of the correlation between molecular structure,detonation performance,and thermal stability.Such insights provide a framework for addressing the inherent trade-offs between these properties.Additionally,the paper highlights the pivotal research direction in heatresistant energetic materials,emphasizing the significance of designing and synthesizing new bridged and nitrogen-fused ring heat-resistant compounds,as well as advancing molecular perovskite-based materials.These endeavors not only offer novel insight for future research but also serve as a guide for the design and synthesis of next-generation heat-resistant energetic materials.

关 键 词：Heat-resistant energetic materials Benzene ring Bridged nitrogen heterocyclic ring Coupled nitrogen heterocyclic ring Fused nitrogen heterocyclic ring Molecular perovskite Energetic metal-organic framework 

分 类 号：TQ560.1[化学工程—炸药化工]