Synthesis and Characterization of Poly(1,4-butylene 2,5-furandicarboxylate-co-isosorbide 2,5-furandicarboxylate)  

作　　者：ZHANG Mengyi CHENG Zhengzai YANG Mian YU Qianwen TAN Zhiping WANDJI DJOUONKEP Lesly Dasilva CHENG Junpeng LIU Panpan DING Ling GAUTHIER Mario 张梦怡;程正载;杨勉

机构地区：[1]Wuhan University of Technology Hospital,Wuhan University of Technology,Wuhan 430070,China [2]The Research Institute of Fine Organic Chemicals&Organic Materials at School of Chemistry and Chemical Engineering,Wuhan University of Science and Technology,Wuhan 430081,China [3]Department of Chemistry,University of Waterloo,Waterloo,Ontario N2L 3G1,Canada

出　　处：《Journal of Wuhan University of Technology(Materials Science)》2025年第2期582-588,共7页武汉理工大学学报(材料科学英文版)

基　　金：Funded by the Program(BG2021)of High-end Foreign Experts of The State Administration of Foreign Experts Affairs(SAFEA);the Young Talent Project of Hubei Provincial Department of Education,China(No.Q20201108)。

摘　　要：High molecular weight poly(1,4-butylene 2,5-furandicarboxylate-co-isosorbide 2,5-furandicarboxylate)copolyesters(PBSIF-x)were synthesized via melt-polycondensation of 2,5-furandicarboxylic acid(FDCA),with varying ratios of isosorbide(ISB)and 1,4-butylene glycol(BDO)catalyzed by antimony trioxide(Sb_(2)O_(3)).The PBSIF-x structures were investigated using FTIR and~1H NMR,while the GPC analysis exhibited the copolyesters molecular weights with number average molecular mass(M_n)in the range of 11079-15153 g/mol.The DSC results show that PBSIF-x copolyesters have a single glass-transition temperature(T_(g))(77.45-110.96℃),increasing with the increase in ISB content,while TGA analysis demonstrates excellent thermal stability up to 320℃.From the thermal result,properties of PBSIF-x copolyesters are found to be within the interval of their parent homologues poly(butylene 2,5-furandicarboxylate)(PBF)and poly(isosorbide 2,5-furandicarboxylate)(PIF),which confirms the aromatic/aliphatic blending within the polymer matrix for enhanced polymer stability and performance.

关 键 词：COPOLYESTER 2 5-furandicarboxylic acid ISOSORBIDE melt polycondensation synthesis and characterization 

分 类 号：O63[理学—高分子化学]