Cobalt selenide confined in nitrogen-doped carbon skeleton as high-rated capability anode for sodium-ion batteries  

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作  者:Jiang-Li Luo Xin-Yu Wang Run-Lin Liu Yu-Han Zeng Huai-Qiang Gu Lei Tan Xin Du Dan Li 

机构地区:[1]College of Chemistry,Zhengzhou University,Zhengzhou,450001,China [2]School of Nuclear Science and Technology,Lanzhou University,Lanzhou,730000,China [3]Institute of Theoretical Physics,Lanzhou University,Lanzhou,730000,China

出  处:《Rare Metals》2024年第12期6742-6750,共9页稀有金属(英文版)

基  金:financially supported by the Natural Science Foundation of Henan Province(No.222300420083);the Opening Foundation of State Key Laboratory of Chemistry and Utilization of Carbon-based Energy Resource of Xinjiang University(No.KFKT2021004)。

摘  要:Cobalt selenide(CoSe_(2))has gained extensive interests due to its high redox reactivity and theoretical capacity.However,its substantial volumetric change during reaction leads to structural instability and consequently inferior cycling performance.In this study,a Co-zeolitic imidazolate framework was synthesized as the precursor via the solvotihermal method and then subjected to a selenizationtreatment to transform into CoSe_(2)nanoparticles.

关 键 词:capacity. SKELETON CONFINED 

分 类 号:O62[理学—有机化学]

 

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