十钨酸在光催化氢原子转移反应中的研究进展  

Research progress of decatungstate in photocatalytic hydrogen atom transfer reactions

作　　者：吴建锋 王俊强 刘锐 余焓 黎玲玲 WU Jianfeng;WANG Junqiang;LIU Rui;YU Han;LI Lingling(College of Chemistry and Materials Science,Shanghai Normal University,Shanghai 200234,China;Instrumental Analysis Center,Shanghai Jiao Tong University,Shanghai 200240,China)

机构地区：[1]上海师范大学化学与材料科学学院,上海200234 [2]上海交通大学分析测试中心,上海200240

出　　处：《上海师范大学学报(自然科学版中英文)》2025年第1期84-95,共12页Journal of Shanghai Normal University(Natural Sciences)

基　　金：国家自然科学基金(22001170)。

摘　　要：光催化氢原子转移(HAT)反应在绿色合成化学、能源转换与存储、环境治理以及生物医学等多个领域具有重要应用价值.近年来,十钨酸化合物作为催化剂在HAT反应中的应用引起了广泛的科学兴趣和关注.研究表明,使用十钨酸盐作为催化剂可以高效促进苯甲醛及其衍生物、环己烷等有机物的HAT反应,为相关领域的发展提供了新的思路和方法.文章旨在系统梳理十钨酸盐催化的HAT反应过程,并评估这类催化剂潜在的应用前景与面临的挑战.Photocatalytic hydrogen atom transfer(HAT)reactions are of substantial application importance in various fields including green synthetic chemistry,energy conversion and storage,environmental management,and biomedical science.In recent years,the use of polyoxotungstate compounds as catalysts in HAT reactions has attracted widespread scientific interest and attention.It was shown that polyoxotungstates,when used as catalysts,can efficiently promote the HAT reactions of benzaldehyde and its derivatives,as well as cyclohexane and other organics,providing new perspectives and methodologies for the advancement of these areas.This review aims to systematically analyze the process of HAT reactions catalyzed by polyoxotungstates and assess the prospects and challenges of these catalysts in potential applications.

关 键 词：十钨酸 氢原子转移(HAT)反应 光催化 苯甲醛 环己烷 

分 类 号：O621.3[理学—有机化学]