金属有机框架材料(MOFs)催化二氧化碳转化的研究进展  

Research progress on metal-organic framework materials for catalyzing carbon dioxide conversion

作　　者：刘琪 黄剑 汪力 王文珍[1,2] 王一凡 李一菲 LIU Qi;HUANG Jian;WANG Li;WANG Wen-zhen;WANG Yi-fan;LI Yi-fei(College of Chemistry and Chemical Engineering,Xi'an Shiyou University,Xi'an 710065,China;Shanxi Provincial Engineering Research Center of Green Low-carbon Energy Materials and Processes,Xi'an 710065,China)

机构地区：[1]西安石油大学化学化工学院,陕西西安710065 [2]陕西省绿色低碳能源材料与过程工程技术研究中心,陕西西安710065

出　　处：《现代化工》2025年第4期69-73,共5页Modern Chemical Industry

基　　金：国家自然科学基金项目(52073228);陕西省自然科学基础研究计划项目(2024JC-YBMS-127)。

摘　　要：金属有机框架(MOFs)由于较大的比表面积、多样化的活性位点和结构可调性,可以将二氧化碳转化为其他有价值的材料。MOFs在催化转化二氧化碳领域的研究进展包括MOFs的结构特点、合成方法及其在二氧化碳加氢、还原、与醇类反应以及环加成生成碳酸脂等反应中的应用,以及MOFs催化剂的活性、选择性和稳定性的调控策略。Metal-organic frameworks(MOFs)can convert carbon dioxide into other valuable materials due to their large specific surface area,diversified active sites and structural adjustability.The reviewed research progress on the application of MOFs in catalytic conversion of carbon dioxide includes the structural characteristics and synthesis methods of MOFs,the applications of MOFs in the reactions such as the hydrogenation and reduction of carbon dioxide,the reaction between carbon dioxide and alcohols,and the cycloaddition of carbon dioxide to generate carbonates,as well as the regulation strategies of activity,selectivity and stability of MOFs catalysts.

关 键 词：二氧化碳 金属有机框架 催化 

分 类 号：O641.4[理学—物理化学]