Recent advances of CuSbS_(2) and CuPbSbS_(3) as photocatalyst in the application of photocatalytic hydrogen evolution and degradation  

作　　者：Xinlong Zheng Zhongyun Shao Jiaxin Lin Qizhi Gao Zongxian Ma Yiming Song Zhen Chen Xiaodong Shi Jing Li Weifeng Liu Xinlong Tian Yuhao Liu 

机构地区：[1]School of Marine Science and Engineering,State Key Laboratory of Marine Resource Utilization in South China Sea,School of Physics and Optoelectronic Engineering,Hainan University,Haikou 570228,China [2]School of Chemical Engineering and Technology,Hainan University,Haikou 570228,China [3]School of Cyberspace Security(School of Cryptology),Hainan University,Haikou 570228,China [4]Mechanical and Electrical Engineering College,Hainan University,Haikou 570228,China

出　　处：《Chinese Chemical Letters》2025年第3期37-51,共15页中国化学快报(英文版)

基　　金：supported by the National Natural Science Foundation of China(Nos.22109034,22109035,52164028,62105083,22202053,52304326,22309037,22305055,52362010);the Startup Research Foundation of Hainan University(Nos.KYQD(ZR)20008,20082,20083,20084,21065,21124,21125);the Innovative Research Projects for Graduate Students of Hainan Province(No.Qhyb2023-20);the Collaborative Innovation Center of Marine Science and Technology of Hainan University(No.XTCX2022HYC21);the first batch of“Nanhai New Star”Industrial Innovation Talent Platform Project(No.NHXXRCXM202309006);the specific research fund of The Innovation Platform for Academicians of Hainan Province。

摘　　要：The realization of high-efficiency photocatalysis is greatly meaningful to overcome the issues of current energy and environment,in which the core factor is the exploration of photocatalysts with promising semiconductor properties.The Cu-based metal sulfide photocatalysts of CuSbS_(2)and its derivative of bournonite CuPbSbS_(3)possess the features of earth-abundant elements,strong photostability,visiblelight range bandgap,and high absorption coefficient,possessing great potential for the realization of efficient photocatalytic applications.Although the photocatalysts of CuSbS_(2)and CuPbSbS_(3)have been investigated in photocatalysis application of hydrogen production and degradation,the exploration process is still in the early-development stage.In this review,the design concept and semiconductor properties of CuSbS_(2)and CuPbSbS_(3)are firstly introduced.Subsequently,the photocatalytic applications of CuSbS_(2)and CuPbSbS_(3)photocatalysts,mainly including hydrogen production and degradation,are systematically reviewed.Finally,the challenges and prospects for the further exploration of CuSbS_(2)and CuPbSbS_(3)photocatalysts are provided.

关 键 词：CuSbS_(2) CuPbSbS_(3) PHOTOCATALYSIS Hydrogen production DEGRADATION 

分 类 号：O643.36[理学—物理化学]