双酚S和双酚AF的环境分布及微生物转化的研究进展  

Research progress on environmental distribution and microbial transformation of bisphenol S and bisphenol AF

作　　者：朱思橙 张晓兰 申秉煜 张颜 张文辉 季荣[1,2] ZHU Sicheng;ZHANG Xiaolan;SHEN Bingyu;ZHANG Yan;ZHANG Wenhui;JI Rong(State Key Laboratory of Pollution Control and Resource Reuse,School of the Environment,Nanjing University,Nanjing,210023,China;Quanzhou Institute for Environmental Protection Industry,Nanjing University,Quanzhou,362000,China)

机构地区：[1]污染控制与资源化研究国家重点实验室,南京大学环境学院,南京210023 [2]泉州南京大学环保产业研究院,泉州362000

出　　处：《环境化学》2025年第3期790-804,共15页Environmental Chemistry

基　　金：十三五国家重点研发计划项目(2021YFA0910300);广东省重点领域研发计划资助(2020B1111380003);泉州市科技计划项目(2020CT002)资助.

摘　　要：双酚S(bisphenol S,BPS)和双酚AF(bisphenol AF,BPAF)是两种使用量最大的双酚A(bisphenol A,BPA)替代品,应用于高分子材料和日常消费品领域,近年来在环境中被广泛检出.相较于其他双酚类物质,BPS和BPAF因其化学结构特性而难以被生物利用,对生态环境和人体健康构成威胁.然而,目前已有少量研究表明在土壤、沉积物和活性污泥中BPS和BPAF可被有效转化.本文在阐述环境中BPS和BPAF的来源和分布的基础上,回顾了已报道的具有转化BPS和BPAF功能的微生物,总结其转化产物和途径,并提出BPS和BPAF转化机制研究中存在的不足以及对未来研究方向的展望,以期为双酚类化合物污染环境的修复提供科学依据.Bisphenol S(BPS)and bisphenol AF(BPAF)have emerged as the primary alternatives to bisphenol A(BPA),finding extensive applications in polymer materials and the manufacturing of daily consumer products.Their widespread presence in the environment has raised concerns in recent years.Notably,the unique chemical structures of BPS and BPAF make them resistant to biotransformation compared to other bisphenol compounds,thereby posing a significant threat to both ecological systems and human health.This paper highlights recent research indicating the potential for effective transformation of BPS and BPAF in soil,sediment,and activated sludge.Based on demonstration of the sources and distribution of BPS and BPAF in the environment,we reviewed microorganisms reported to possess the ability to transform these compounds,and summarized products and pathways associated with this transformation.Additionally,challenges and opportunities were proposed for further exploration into the biotransformation mechanisms of BPS and BPAF.In summary,this review serves as a scientific foundation for developing strategies to remediate environments contaminated with bisphenol compounds.

关 键 词：双酚S 双酚AF 环境分布 生物降解机制 降解菌 转化途径. 

分 类 号：X-1[环境科学与工程] O6[理学—化学]