无氟抗油污表面制备方法及其研究进展  

Research Progress for Design and Fabrication of Fluorine-Free Surfaces with Oil-Repellent Property

作　　者：王庆 李鹏 吴大伟 姜露 方新锐 牛海涛[1,2] 周华 Qing Wang;Peng Li;Dawei Wu;Lu Jiang;Xinrui Fang;Haitao Niu;Hua Zhou(Laboratory for Manufacturing Low Carbon and Functionalized Textiles in the Universities of Shandong Province/Collaborative Innovation Center for Eco-textiles of Shandong Province and the Ministry of Education Collaborative,College of Textiles&Clothing,Qingdao University,Qingdao 266071,China;National Innovation Center of Advanced Dyeing and Finishing Technology,Tai'an 271000,China;Lerune(Qingdao)Textile Technology Co,Ltd.,Qingdao 266071,China)

机构地区：[1]青岛大学山东省高等学校低碳纺织与功能制造实验室/生态纺织省部共建协同创新中心,青岛266071 [2]国家先进印染技术创新中心,泰安271000 [3]联润翔(青岛)纺织科技有限公司,青岛266071

出　　处：《化学进展》2025年第2期255-280,共26页Progress in Chemistry

基　　金：国家自然科学基金项目(No.22372087)资助;supported by the National Natural Science Foundation of China(No.22372087)。

摘　　要：氟化物由于其极低的表面能因而具有卓越的防水和抗油污能力,在功能整理领域广泛应用。然而,氟的使用会对人类健康构成潜在威胁,并对环境造成不可逆转的破坏,因此正逐渐被各国限制使用,寻找无氟替代品已成为防水抗污等领域亟待解决的关键问题。为明晰无氟抗油污材料的定义并挖掘其在化学领域的应用潜力,探讨了无氟抗油污表面的研究背景,并对近期的研究成果和制备方法进行了综述和评价,对无氟抗油污材料表面的制备机理进行分析,概述了其在纺织、建筑、食品及液体处理等领域中的应用现状,剖析了现阶段无氟抗油污研究所面临的挑战,最低对绿色环保型无氟抗油污技术的未来进行了展望。The exceptional waterproof and oil-repellent properties of fluorides, attributed to their remarkably low surface energy, have rendered them extensively employed in the realm of functional finishing. However, the use of fluorine presents potential hazards to human health and engenders irreversible harm to the environment.Consequently, it is progressively being regulated by nations, and discovering alternatives without fluorine has emerged as an imperative concern that necessitates immediate attention in the fields of waterproofing and anti-fouling. To clarify the definition of the fluorine-free materials with oil-repellent property and explore their potential applications in the field of chemistry, the research background of fluorine-free surfaces with oil-repellent property was described, along with a comprehensive review and evaluation of recent achievements and preparation methods. Furthermore, the mechanism of fluorine-free surfaces with oil-repellent property was analyzed, and the application status of fluorine-free coating with oil-repellent property in textiles, construction,food, liquid treatment and other fields was summarized. Additionally, an analysis of the current challenges in ongoing research process of fluorine-free surfaces with oil-repellent property was provided. Finally, a prospective outlook on the future of green and environmentally-friendly fluorine-free surface technology was prospected.

关 键 词：无氟 抗油污 低表面能 粗糙度 液体表面 “类液体”表面 

分 类 号：TB34[一般工业技术—材料科学与工程]