素馨烯及杂化素馨烯的合成  

Synthesis of sumanene and hetera-sumanene

作　　者：李雪锋[1] 杨鹏 王文博 LI Xuefeng;YANG Peng;WANG Wenbo(School of Chemistry and Environment,Southwest Minzu University,Chengdu 610041,China)

机构地区：[1]西南民族大学化学与环境学院,四川成都610041

出　　处：《西南民族大学学报(自然科学版)》2025年第2期140-152,共13页Journal of Southwest Minzu University(Natural Science Edition)

基　　金：西南民族大学中央高校基本科研业务费专项资金资助(ZYN2023028)。

摘　　要：相较于平面共轭稠环芳烃,“碗状”分子具有独特的几何结构与光电性质,广泛应用于有机功能材料的合成与开发中.利用主族元素固有的性质差异,将杂原子嵌入到“碗状”分子的π共轭骨架中,是有效调控该类型功能分子理化性质的手段之一.围绕“碗状”分子的代表性化合物——素馨烯的合成研究进展,重点综述了主族元素掺杂的素馨烯的构建策略.Buckybowls display unique structural and optoelectronic features as compared to planar polycyclic aromatic hydrocarbons,and they are key building blocks for organic functional materials.Heteroatom incorporation to π-framework is an efficient route to modify its inherent properties,because the structure and properties of the resultant hetera-buckybowls are greatly influenced by the heteroatoms' nature.In this review,we will introduce the advances in synthetic strategies toward sumanene frameworks,especially focusing on doped sumanene with heteroatoms.

关 键 词：碗状分子 素馨烯 杂化素馨烯 

分 类 号：O621.3[理学—有机化学]