磷酸胍阻燃布料复配配方开发及其应用研究  

Development and application of compound formulation of flame retardant cloth with guanidine phosphate

作　　者：牛鹏英 龙德晓 万邦隆 马航 孔垂杨 毛顿 马新蕊 梅连平 NIU Pengying;LONG Dexiao;WAN Banglong;MA Hang;KONG Chuiyang;MAO Dun;MA Xinrui;MEI Lianping(R&D Center,Yunnan Yuntianhua Co.,Ltd.,Kunming 650228,China)

机构地区：[1]云南云天化股份有限公司研发中心,云南昆明650228

出　　处：《生态产业科学与磷氟工程》2025年第3期36-40,72,共6页Eco-industry Science & Phosphorus Fluorine Engineering

摘　　要：采用自主生产的磷酸胍产品开展阻燃剂添加量确定、复配配方开发等工作,同时对阻燃布料的制备工艺参数(浸渍时间、压轧压强、高温固化温度)进行优化,制备一款适用于纯棉布的磷酸胍复配阻燃剂(GP-1-BL)。在m(磷酸胍)∶m(协效剂A)∶m(水)=7∶5∶100、浸渍时间90 s、压轧压强0.2 MPa、高温固化温度130℃条件下,添加12份复配阻燃剂的阻燃布料的极限氧指数与垂直燃烧测试结果可满足GB/T 17591—2006燃烧性能要求B1等级、GB 20286—2006阻燃织物1级要求。GP-1-BL阻燃效率高,对布料外观颜色影响小,价格相对较低,具有较好的市场推广前景。A guanidine phosphate compound flame retardant(CP-1-BL)suitable for pure cotton cloth is prepared by determining the addition amount of flame retardants and developing the compound formulation with guanidine phosphate.At the same time,the preparation process parameters(immersion time,rolling pressure,high-temperature curing temperature)of flame retardant cloth are optimized.The ultimate oxygen index and vertical combustion test results of flame retardant cloth with 12 pieces of GP-1-BL can meet the combustion performance requirements of GB/T 17591-2006 B1 class and GB 20286—2006 flame retardant fabric class 1 under the conditions of that the mass ratio of guanidine phosphate,synergist A and water is 7:5:100,immersion time is 90 s,rolling pressure is 0.2 MPa,high-temperature curing temperature is 130℃.GP-1-BL has high flame retardant efficiency,little influence on the appearance color of cloth,relatively low price,and has a good market promotion prospect.

关 键 词：磷酸胍 阻燃 布料 复配配方 应用 

分 类 号：TQ126.35[化学工程—无机化工]