Study on the Improvement of Foaming Properties of PBAT/PLA Composites by the Collaboration of Nano-Fe_(3)O_(4) Carbon Nanotubes  

作　　者：Jiahao Liu Xinyu Zhang Huiwei Wang Yupeng Li Shan Jin Guanxian Qiu Ce Sun Haiyan Tan Yanhua Zhang 

机构地区：[1]Key Laboratory of Bio-Based Material Science&Technology,Northeast Forestry University,Ministry of Education,Harbin,150040,China [2]Northeast Forestry University Engineering Consulting and Design Research Institute Co.,Ltd.,Harbin,150040,China

出　　处：《Journal of Renewable Materials》2025年第4期669-685,共17页可再生材料杂志(英文)

基　　金：funded by National Undergraduate Training Programs for Innovations(Northeast Forestry University,grant number 202410225023);funded by Young Elite Scientist Sponsorship Program by Heilongjiang Province(2024QNTG006);the Fundamental Research Funds for the Central Universities(2572024DP05);funded by The Collaborative Innovation Project of First-Class Disciplines in Heilongjiang Province(LJGXCG2024-F11).

摘　　要：In recent years,degradable materials to replace petroleum-based materials in preparing high-performance foams have received much research attention.Degradable polymer foaming mostly uses supercritical fluids,especially carbon dioxide(Sc-CO_(2)).The main reason is that the foams obtained by Sc-CO_(2) foaming have excellent performance,and the foaming agent is green and pollution-free.In current research,Poly(butylene adipate-co-terephthalate)(PBAT),poly(lactic acid)(PLA),and other degradable polymers are generally used as the main foaming materials,but the foaming performance of these degradable polyesters is poor and requires modification.In this work,10%PLA was added to PBAT to enhance the melt strength and improve the foaming performance.To improve the foaming properties of the PBAT/PLA composites,two kinds of nano-filler(nano-Fe_(3)O_(4) and carbon nanotubes(CNTs))were innovatively introduced for foaming modification.There was a synergistic effect between the two nano-fillers to enhance the foaming properties significantly.When 6 wt%CNTs and 4 wt%nano-Fe_(3)O_(4) were added,the 4Fe_(3)O_(4)/6CNT foam had the best comprehensive performance.Its foaming rate reached 14.8 times,which was 2.8 and 2.1 times that after adding 10 wt%CNTs or 10 wt%nano-Fe_(3)O_(4) alone.The combined action could adjust the melt elasticity of different PBAT/PLA composites to the optimum.The nanofillers also served as skeleton structures to support the foam cells,significantly improving the foaming performance.The density and foaming ratio did not change significantly at 14 days after foaming.The compressive strength of the composite foam reached up to 0.27 MPa and the water contact angle reached 120.1°.The synergistic foaming effect of nano-Fe_(3)O_(4) and CNTs could significantly improve the Sc-CO_(2) foaming performances of the composites,providing a new method for degradable materials to replace petroleum-based materials.

关 键 词：Poly(lactic acid) poly(butylene adipate-co-terephthalate) supercritical carbon dioxide 

分 类 号：TQ328[化学工程—合成树脂塑料工业]