New Rigid Furan Biofoams Based on Hydrolysable Chesnut(Castanea sativa)Tannin by Chemical Expansion  

作　　者：João Vitor Dorini Falavinha Pedro Henrique Gonzales De Cademartori Philippe Gérardin Antonio Pizzi Christine Gérardin-Charbonnier 

机构地区：[1]UR 4370 USC 1445 LERMAB,INRAE,Facultédes Sciences et Technologies,Universitéde Lorraine,Nancy,54506,France [2]GNanoAgro,Universidade Federal do Paraná,Curitiba,82590,Brazil

出　　处：《Journal of Renewable Materials》2025年第4期687-697,共11页可再生材料杂志(英文)

基　　金：supported by a grant overseen by the French National Research Agency(ANR),as part of the“Investissements d’Avenir”program(ANR-11-LABX-0002-01,Lab of Excellence ARBRE);supported by“Lorraine Universitéd’Excellence”Master Grant,ORION program and by the French Ministry of Foreign Office through EIFFEL program.

摘　　要：Tannins are polyphenols widely present in the plant kingdom,commonly divided into two groups:condensed and hydrolysable tannins.Sustainable furanic bio-foams based on condensed tannins have been largely studied,but little is described about the use of hydrolysable tannins for this material.This study examined the potential of hydrolysable chestnut tannin in comparison to condensed mimosa tannins to produce furanic foams by chemical expansion.Due to the low reactivity of the hydrolysable tannin,the use of an external source for its polymerization and curing was necessary.Through Fourier transform infrared spectroscopy(FTIR)chromatography,it was possible to observe that the new foams presented small differences in functional groups compared to the condensed tannin foams,presenting peaks related to carboxyl groups.In terms of physical properties,the chestnut foams showed an apparent density 36%higher than the conventional mimosa tannin foams and a superior hydrophilic character.In terms of thermal properties,both foams exhibit high thermal stability,with the acacia tannin foam being slightly superior.In summary,this research paves the way for new applications of hydrolysable tannins in bio-foams and materials science.

关 键 词：Tannin foams furfuryl alcohol hydrolysable tannin CHESTNUT 

分 类 号：TQ35[化学工程]