3-Acetamido-5-acetylfuran: An emerging renewable nitrogen-containing platform compound  

作　　者：Jinhang Dai Qingya Cao Delong Yang Gang Chen Ziting Du Song Wang Fukun Li 

机构地区：[1]College of Environment and Resources,Chongqing Technology and Business University,Chongqing 400067,China

出　　处：《Chinese Journal of Chemical Engineering》2025年第2期263-272,共10页中国化学工程学报(英文版)

基　　金：support of the National Natural Science Foundation of China(22408032);the Science and Technology Research Program of Chongqing Municipal Education Commission(KJQN202000826 and KJQN202300836);Research Start-up Funding project of Chongqing Technology and Business University(1856011);Science and Technology Project of Chongqing Technology and Business University(2152027);Graduate Innovative Research Project from Chongqing Technology and Business。

摘　　要：In the last decade,shell biorefinery,a novel concept referring to the extraction of the main components of crustacean shells and the transformation of each component into valuable products,was proposed and has attracted increasing attentions.Chitin is one of main components of crustacean shells.Owing to the bio-fixed nitrogen element,chitin biomass has been regarded as a good candidate to produce nitrogen-containing chemicals.Among these,3-acetamido-5-acetylfuran(3A5AF)is an interesting furanic compound derived from the hydrolysis and sequential dehydration of chitin.Similar to cellulose-derived platform chemical 5-hydromethylfurfural(HMF),3A5AF is an emerging platform compound and also can be converted into various useful chemicals by oxidation,reduction,hydrolysis,substitution,and so on.This review showcases the recent advances in the synthesis of 3A5AF from chitin and N-acetyl glucosamine(NAG)employing various catalytic systems.The conversion of 3A5AF into valuable compounds was introduced then.There are still some challenges in this area,for example,the rational design of green and efficient catalytic systems for the synthesis of 3A5AF and its derivatives.The outlooks also were discussed at the end of the review.

关 键 词：Biomass CHITIN Shell biorefinery Platform compound 

分 类 号：O62[理学—有机化学]