次氯酸钠法制备橡胶促进剂CBS的研究  

The research on the Preparation of Rubber Accelerator CBS by the Sodium Hypochlorite Method

作　　者：孙晓彤[1] 高宇 薛鹏程 张卓尔 刘岩军 刘燕灼 张庆伟 黎振球[1] 范金石[1,4] SUN Xiaotong;GAO Yu;XUE Pengcheng;ZHANG Zhuoer;LIU Yanjun;LIU Yanzhuo;ZHANG Qingwei;LI Zhenqiu;FAN Jinshi(College of Biological Engineering,Qingdao University of Science and Technology,Qingdao 266042,China;Dalian Institute of Chemical Physics,University of Chinese Academy of Sciences,Dalian 116041,China;Shandong Fine Chemical Technology Co.,Ltd.,Weifang 262618,China;State Key Laboratory Base for Eco-chemical Engineering,Qingdao University of Science and Technology,Qingdao 266042,China)

机构地区：[1]青岛科技大学生物工程学院,山东青岛266042 [2]中国科学院大学大连化学物理研究所,辽宁大连116041 [3]山东法恩新材料科技有限公司,山东潍坊262618 [4]青岛科技大学省部共建生态化工国家重点实验室培育基地,山东青岛266042

出　　处：《山东化工》2025年第6期20-23,共4页Shandong Chemical Industry

基　　金：山东省科技型中小企业创新能力提升工程项目(2022TSGC2390)。

摘　　要：为了优化传统的次氯酸钠法制备橡胶促进剂环己基-2-苯并噻唑次磺酰胺(CBS)的工艺,以2-巯基苯并噻唑(促进剂M)和环己胺为原料,以异丙醇为溶剂的条件下,进行了不同催化剂在不同反应条件下对次氯酸钠法氧化制备CBS生产工艺的性能研究,通过改变原料配比、溶剂含量、温度、催化剂种类等因素,设计相关正交实验,经熔点、游离胺及液相色谱的测定,确定优化反应条件及催化剂种类。结果:次氯酸钠法制备CBS的优化组合为M、环己胺物质的量比1∶1.2,M、NaClO物质的量比1∶1.4、溶剂选用100%异丙醇,含量为85%、反应温度设为45℃、催化剂选用氢氧化锰。In order to optimize the traditional sodium hypochlorite method for preparing rubber accelerator cyclohexyl-2-benzothiazole sulfonamide(CBS),we used 2-mercaptobenzothiazole(promoter M)and cyclohexylamine as raw materials and isopropanol as solvent,studying the performance of different catalysts in the production process of CBS by sodium hypochlorite oxidation under different reaction conditions,By changing the raw material ratio,solvent content,temperature,catalyst type and other factors,relevant orthogonal experiments are designed.The optimal reaction conditions and catalyst types are determined by measuring the melting point,free amine and liquid chromatography.The optimal combination for preparing CBS by sodium hypochlorite method was determined through result analysis as n(M)∶n(cyclohexylamine)=1∶1.2,n(M)∶n(NaClO)=1∶1.4,solvent selected as 100%isopropanol with a content of 85%,reaction temperature set as 45℃,and catalyst selected as manganese hydroxide.

关 键 词：次氯酸钠法 正交试验 异丙醇 促进剂CBS 催化剂 

分 类 号：TQ330.385[化学工程—橡胶工业]