Easy Access to Phenanthrenes Through Photoinduced Difunctionalization of Alkynes  

可见光引发炔烃双官能化反应构筑菲类化合物(英文)

作　　者：Mengqian Li Zhe Lv Shaojun Wang Yuxuan Han Xiuling Cui 李梦倩;吕喆;王少君;韩宇轩;崔秀灵(华侨大学生物医学学院、分子药物教育部工程研究中心、福建省分子医学重点实验室、福建省高校精准医学与分子诊断重点实验室、厦门市海洋与基因药物重点实验室,福建厦门361021)

机构地区：[1]Key Laboratory of Xiamen Marine and Gene Drugs,Key Laboratory of Precision Medicine and Molecular Diagnosis of Fujian Universities,Engineering Research Center of Molecular Medicine,Ministry of Education,Key Laboratory of Fujian Molecular Medicine,School of Biomedical Sciences,Huaqiao University,Xiamen,Fujian 361021

出　　处：《有机化学》2025年第2期686-693,共8页Chinese Journal of Organic Chemistry

基　　金：福厦泉国家自主创新协同创新项目(3502ZCQXT2021006);高等学校学科创新引智计划(111计划);高等学校学科创新引智计划(BC2018061);华侨大学开放基金(AACCT0007)。

摘　　要：Ketoesters were successfully utilized as the bifunctionalization reagents to react with diaryl alkynes under visible light and photocatalyst or additives free conditions. A series of phenanthrenes containing acyl and ester groups were obtained in high yields. This protocol features with excellent regioselectivity, high efficiency, and atomic economy.酮酯作为双官能团化试剂,在可见光下与二芳基炔烃反应,以高产率获得一系列含有酰基和酯基的菲类化合物.该策略不需要添加额外的光催化剂以及添加剂,具有优秀的区域选择性、高效率和原子经济性.

关 键 词：visible-light-promoted bifunctional reaction carbon-carbon bond activation PHENANTHRENES 

分 类 号：O621.3[理学—有机化学]