生物基(甲基)丙烯酸酯的合成及其聚合物制备  

Synthesis and Polymerizations of Bio-Based(meth)Acrylates

作　　者：杨雨尘 刘振杰[4] 陆春华[1,3] 郭凯 胡欣[1,3] 朱宁 Yuchen Yang;Zhenjie Liu;Chunhua Lu;Kai Guo;Xin Hu;Ning Zhu(College of Materials Science and Engineering,Nanjing Tech University,Nanjing 211800,China;College of Biotechnology and Pharmaceutical Engineering,Nanjing Tech University,Nanjing 211800,China;State Key Laboratory of Materials-Oriented Chemical Engineering,Nanjing 211800,China;SINOPEC(Beijing)Research Institute of Chemical Industry Co.,Ltd.,Beijing 100013,China)

机构地区：[1]南京工业大学材料科学与工程学院,南京211800 [2]南京工业大学生物与制药工程学院,南京211800 [3]材料化学工程全国重点实验室,南京211800 [4]中石化(北京)化工研究院有限公司,北京100013

出　　处：《化学进展》2025年第3期383-396,共14页Progress in Chemistry

基　　金：国家自然科学基金项目(No.22478188,22278205,22278223);中国石化委托开发项目(No.36600000-25-ZC0607-0047,30000000-23-ZC0607-0871,420106);化学品安全全国重点实验室(中石化安全工程研究院有限公司)资助。

摘　　要：作为合成高分子的重要品种,(甲基)丙烯酸酯聚合物在涂料、黏合剂、生物医用、电子电气材料等领域应用广泛。然而,目前(甲基)丙烯酸酯单体主要来源于不可再生的石化资源,从可持续发展角度而言,将生物质转化为(甲基)丙烯酸酯单体及其聚合物具有重要意义,不仅可以作为石化材料的补充,并且通过结构设计有望获得高性能的系列材料,提高产品附加值。本文总结了近年来生物基(甲基)丙烯酸酯及其聚合物的研究进展,系统介绍了以木质素、萜烯、植物油、葡萄糖、异山梨醇、呋喃化合物等生物质为原料生物基(甲基)丙烯酸酯单体的合成,探讨了上述单体聚合产物的性能与应用,并对相关领域面临的挑战与发展前景进行了展望。As an important family of synthetic polymers,poly(meth)acrylates have a wide range of applications in the fields of coatings,adhesives,biomedines,electronic and electrical materials.However,the(meth)acrylates monomers are mainly derived from petrochemical resources.Transformations of biomass into(meth)acrylate monomers and polymers have attracted growing research interest from the viewpoint of sustainability.The bio-based poly(meth)acrylates not only serve as the supplement for the fossil based product but also provide great chance for the development of value-added high performance materials with designed novel structures.This article highlights the recent progress in the synthesis and polymerization of bio-based(meth)acrylates.The lignin,terpene,plant oil,glucose,isosorbide,and furan derivatives as the biomass feedstock are respectively reviewed in consecutive order.The properties and applications of the corresponding bio-based poly(meth)acrylates are summarized.Moreover,the challenges and opportunities of bio-based poly(meth)acrylates are also discussed.

关 键 词：生物质转化 (甲基)丙烯酸酯 自由基聚合 生物基材料 

分 类 号：O632[理学—高分子化学] TQ325.7[理学—化学]