Zr-4合金微动磨损特性实验研究  

Experimental Study on Fretting Wear Characteristic of Zr-4 Alloy

作　　者：刘海东 贺凯 伏锦胜 李正阳 蒲曾坪[3] 任全耀 陈德奇[4] 汪宁远 LIU Haidong;HE Kai;FU Jinsheng;LI Zhengyang;PU Zengping;REN Quanyao;CHEN Deqi;WANG Ningyuan(Liangjiang International College,Chongqing University of Technology,Chongqing 401135,China;The Joint Graduate Training Base for Energy and Power(Clean Energy Technology)between Chongqing University of Technology and Chongqing Research Institute of Harbin Institute of Technology,Chongqing 401135,China;Science and Technology on Reactor System Design Technology Laboratory,Nuclear Power Institute of China,Chengdu 610213,China;Key Laboratory of Low-grade Energy Utilization Technologies and Systems,Ministry of Education,Chongqing University,Chongqing 400044,China)

机构地区：[1]重庆理工大学两江国际学院,重庆401135 [2]重庆理工大学-哈尔滨工业大学重庆研究院能源动力(清洁能源技术领域)研究生联合培养基地,重庆401135 [3]中国核动力研究设计院核反应堆系统设计技术重点实验室,四川成都610213 [4]重庆大学低品位能源利用技术及系统教育部重点实验室,重庆400044

出　　处：《原子能科学技术》2025年第4期891-899,共9页Atomic Energy Science and Technology

基　　金：重庆市自然科学基金面上项目(CSTB2023NSCQ-MSX0649);中国博士后科学基金面上项目(2024M751537);重庆市教委科学技术研究计划(KJQN202401126)。

摘　　要：核燃料棒包壳微动磨损特性对反应堆系统安全性至关重要。为研究Zr-4合金包壳微动磨损特性,本文通过搭建微动磨损实验装置,采用线接触方式开展Zr-4合金微动磨损实验研究,针对不同位移幅值研究Zr-4合金微动磨损的微观形貌和元素变化及其磨损机制。结果表明:位移幅值增大导致磨损现象加剧,最大磨损深度和磨损体积增加,尤其在加速磨损区Zr-4合金微动损伤加速恶化,最大磨损深度和磨损体积的增长速率分别达到峰值0.34μm/μm、0.52×10^(-2) mm^(3)/μm。整个微动磨损过程中,磨损区域均伴随着Zr、Fe、Cr等金属氧化物的产生,局部磨损区域存在磨屑的转移与黏着。低磨损区的整个损伤区域被平滑的三体层覆盖;加速磨损区的整个损伤区域存在凹痕形成和三体层动态变换现象;稳定磨损区的损伤中心区域三体层发生片状脱落,并伴有微观裂纹萌生。本文研究结果为Zr-4合金包壳在压水堆服役中的微动磨损行为提供了数据参考。Nuclear energy,as a safe,clean,and efficient low-carbon energy source,has become an important option for achieving sustainable energy and power development.However,during the operation of pressurized water reactors,flow-induced vibrations can trigger fretting wear behavior in Zr-4 alloy cladding,causing damage to the contact surface and leading to the failure of nuclear fuel assemblies,potentially resulting in the leakage of nuclear fission products.To investigate the fretting wear characteristics of Zr-4 alloy cladding,a fretting wear experimental device was independently designed and constructed for studying the wear behavior of Zr-4 alloy under line contact with different displacement amplitudes.The fretting wear of Zr-4 alloy was divided into three zones based on displacement amplitude:low wear zone,accelerated wear zone,and stable wear zone.A white light interferometer was used to obtain the 3D morphology and wear quantities(wear volume and maximum wear depth) of the damaged areas,while scanning electron microscopy(SEM) and energy dispersive spectroscopy(EDS) were used to analyze the microscopic morphology and elemental distribution of the damaged areas.The microstructural characteristics of the fretting wear zones in Zr-4 alloy were studied,focusing on the changes in micro-morphology,elemental composition,and wear mechanisms.The results indicate that an increase in displacement amplitude intensifies the wear phenomena,with maximum wear depth and wear volume increasing.Particularly,in the accelerated wear zone,fretting wear to Zr-4 alloy deteriorates more rapidly.The growth rates of both maximum wear depth and wear volume reach their peak and then decrease.Throughout the fretting wear process,metal oxides such as Zr,Fe,and Cr are generated and removed from the wear zones.The Fe content in the damaged area gradually decreases and stabilizes,while the oxygen content initially increases,reaching a peak in the accelerated wear zone before beginning to decrease.In localized wear zones,the transfer and adhesion of

关 键 词：包壳 ZR-4合金 微动磨损 磨损机制 

分 类 号：TL341[核科学技术—核技术及应用]