反应型阻燃剂磷酸三(间羟基)苯酯的绿色制备过程  

Study on Green Synthesis of Reactive Phosphorous Flame-Retardant Tris-(m-hydroxy phenyl)Phosphate

作　　者：沈琴艳 张玉涛 刁潘燕 唐综妍 黄群芳 吴县燕 胡玉林 SHEN Qinyan;ZHANG Yutao;DIAO Panyan;TANG Zongyan;HUANG Qunfang;WU Xianyan;HU Yulin(College of Chemistry and Chemical Engineering,Key Laboratory of Agricultural Resources and Environment in High Education Institute of Guizhou Province,Anshun University,Anshun Guizhou 561000,China)

机构地区：[1]安顺学院化学化工学院,贵州省高等学校农业资源与环境研究重点实验室,贵州安顺561000

出　　处：《辽宁化工》2025年第4期599-601,共3页Liaoning Chemical Industry

基　　金：安顺学院贵州省2023年大学生创新创业训练计划项目(项目编号:S202310667051);贵州省高等学校农业资源与环境研究重点实验室项目(项目编号:黔教技[2023]025);贵州省高等学校多孔材料与绿色催化创新团队项目(项目编号:黔教技[2023]086号)。

摘　　要：旨在介绍一种温和的条件下催化合成磷酸三(间羟基)苯酯(THPP)的方法。该方法以设计制备的金属有机骨架材料ZIF-7为催化剂,催化间苯二酚与三氯氧磷进行一步反应得到目标化合物,产物收率可达58%。催化剂ZIF-7具有制备方法简单、稳定性好、回收利用便捷等优点,符合绿色化学的发展方向,具有良好的应用前景。A type of metal-organic frameworks ZIF-7 has been synthesized and efficiently used as an catalyst in the one-pot synthesis of tris-(m-hydroxy phenyl)phosphate(THPP)in the reaction of resorcinol and phosphorus oxychloride.It was shown that the good efficiency with product yield of 58%was achieved under mild conditions.The advantages of ZIF-7 are simple preparation method,excellent biocompatibility and convenient recycling,which meet the development direction of green chemistry and possess good application prospects.

关 键 词：金属有机骨架材料ZIF-7 非均相催化 磷酸三(间羟基)苯酯 环境友好 

分 类 号：TQ032.41[化学工程]