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作 者:贺鑫 陈西杰 王焱 HE Xin;CHEN Xijie;WANG Yan(Anhui Kaize New Materials Limited Company,Huaibei 235000,China)
机构地区:[1]安徽凯泽新材料有限公司,安徽淮北235000
出 处:《橡胶工业》2025年第5期391-397,共7页China Rubber Industry
摘 要:综述防静电丁腈胶乳手套3种制备方法的研究进展。防静电涂层法是较为简便的丁腈胶乳手套的制备方法,通过添加防静电涂层或其他类型涂层可提高丁腈胶乳手套的抗静电性能和其他功能性,但需考虑不同涂层间的附着力和兼容性,避免涂层脱落。乳液混合法是最常用的防静电丁腈胶乳手套的制备方法,在丁腈胶乳配合过程中加入导电填料、抗静电剂或自由基清除剂可避免丁腈胶乳手套的电荷积累,但需考虑防静电丁腈胶乳手套的颜色较深、抗静电剂与丁腈胶乳的相容性等问题。原位聚合法是丁腈胶乳手套研究最少、难度最高的制备方法,其制备的胶乳更稳定、导电填料分布更均匀,但需要提前对导电填料进行预处理或改性,将其乳化到聚合体系中,使制备的手套具有防静电能力。The research progress of three preparation methods for anti-static nitrile latex gloves was reviewed.The anti-static coating method was a relatively simple method for preparing nitrile latex gloves,which improved the anti-static performance and other functionalities of nitrile latex gloves by adding antistatic coating or other types of coatings.However,the adhesion and compatibility between different coatings needed to be considered to avoid coating detachment.The emulsion mixing method was the most commonly used method for preparing anti-static nitrile latex gloves.Conductive fillers,anti-static agents or free radical scavengers were added during the process of preparing nitrile latex to avoid the accumulation of electric charges in nitrile gloves.However,challenges such as the darker color of anti-static nitrile latex gloves and the compatibility between anti-static agents and nitrile latex had to be addressed.The in-situ polymerization method was found to be the least studied and most challenging preparation method for nitrile latex gloves,which produced more stable latex and a more uniform distribution of conductive fillers.However,prior treatment or modification of conductive fillers was required to emulsify them into the polymerization system,ensuring the resulting gloves possessed anti-static properties.
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