蒙脱土对丙烯酸树脂感湿材料性能的改善作用  

Effect of Montmorillonite on Improving Properties of Acrylic Resin Moisture Sensing Materials

作　　者：马旭 魏丹蕊 曹立久 桑柳波 唐毅 王波 陈玉放[1,2,3,4,5,6,7] MA Xu;WEI Danrui;CAO Lijiu;SANG Liubo;TANG Yi;WANG Bo;CHEN Yufang(Guangzhou Institute of Chemistry,Chinese Academy of Sciences,Guangzhou 510650,China;University of Chinese Academy of Sciences,Beijing 100049,China;CAS Testing Technical Services(Guangzhou)Co.Ltd,Guangzhou 510650,China;CAS Engineering Laboratory for Special Fine Chemicals,Guangzhou 510650,China;CASH GCC Shaoguan Research Institute of Advanced Materials,Shaoguan 512400,China;CASH GCC Fine Chemicals Incubator(Nanxiong)Co.,Ltd,Nanxiong 512400,China;New Materials Research Institute of CASCHEM(Chongqing)Co.,Ltd.,Chongqing 400714,China)

机构地区：[1]中国科学院广州化学研究所,广东广州510650 [2]中国科学院大学,北京101408 [3]中科检测技术服务(广州)股份有限公司,广东广州510650 [4]中国科学院新型特种精细化学品工程实验室,广东广州510650 [5]国科广化韶关新材料研究院,广东韶关512400 [6]国科广化精细化工孵化器(南雄)有限公司,广东南雄512400 [7]中科广化(重庆)新材料研究院有限公司,中国重庆400714

出　　处：《广州化学》2025年第2期1-6,I0001,共7页Guangzhou Chemistry

基　　金：重庆自然科学基金(CSTB2022NSCQ-MSX0986)。

摘　　要：用蒙脱土(MMT)改进丙烯酸树脂(PAC)感湿材料的性能,以进一步提高其湿敏响应特性。结果表明:在11%RH~95%RH湿度范围内,所制备的PAC@MMT复合材料的感湿响应时间为1.5 s,较PAC湿敏器件提升了3.33倍;在30%RH~95%RH湿度范围内,PAC@MMT湿敏器件的灵敏度为73.66 kΩ/%RH,显著高于PAC湿敏器件的30.66 kΩ/%RH,平均功耗为41.77μW,明显低于PAC湿敏器件的71.68μW,相关系数r=0.9941;同时,PAC@MMT湿敏器件拥有优异的热稳定性与长期稳定性。In this paper,montmorillonite(MMT)was used to improve the performance of acrylic resin(PAC)humidity sensitive material,so as to further improve its humidity sensitive response.The results show that in the humidity range of 11%RH~95%RH,the humidity sensing response time of PAC@MMT composite is 1.5 s,which is 3.33 times higher than that of PAC.In the humidity range of 30%RH~95%RH,the sensitivity of PAC@MMT humidity sensor is 73.66 kΩ/%RH,which is significantly higher than that of PAC humidity sensor(30.66 kΩ/%RH),and the average power consumption is 41.77μW,which is significantly lower than that of PAC humidity sensor(71.68μW).The linear correlation coefficient reaches r=0.9941.At the same time,PAC@MMT humidity sensitive devices have excellent thermal stability and long-term stability.

关 键 词：聚丙烯酸感湿树脂 蒙脱土 复合湿敏材料 湿敏性能 

分 类 号：TQ323.6[化学工程—合成树脂塑料工业]