过渡金属基电极电催化氧化5-羟甲基糠醛为2,5-呋喃二甲酸研究进展  

Transition Metal-based Electrodes for Electrocatalytic Oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic Acid

作　　者：漆新华[1] 王浩业 冯艺璇 QI Xinhua;WANG Haoye;FENG Yixuan(College of Environmental Science and Engineering,Nankai University,Tianjin 300350;State Key Laboratory of Nutrient Use and Management,Key Laboratory of Wastes Matrix Utilization,Ministry of Agriculture and Rural Affairs,Institute of Agricultural Resources and Environment,Shandong Academy of Agricultural Sciences,Jinan 250100,Shangdong)

机构地区：[1]南开大学环境科学与工程学院,天津300350 [2]山东省农业科学院农业资源与环境研究所,养分资源高效利用全国重点实验室,农业农村部废弃物基质化利用重点实验室,山东济南250100

出　　处：《四川师范大学学报(自然科学版)》2025年第4期427-439,F0002,共14页Journal of Sichuan Normal University(Natural Science)

基　　金：国家自然科学基金(22178181);天津市自然科学基金(21JCZDJC00180);中央高校基本科研业务费(南开大学63243129)。

摘　　要：从可持续生物质或生物质衍生平台化学品中制备增值化学品对缓解化石燃料枯竭具有重要意义.5-羟甲基糠醛(HMF)是一种重要的生物基平台分子,因其氧化产物2,5-呋喃二甲酸(FDCA)可作为石油衍生对苯二甲酸(TPA)的可持续替代品而受到广泛关注.相比于传统的热催化转化,电化学催化具有环境友好、反应条件温和以及反应系统可控性强等优点,将其用于高效催化HMF合成FDCA在很大程度上可以降低能源成本和环境影响.本综述讨论HMF的电化学氧化,介绍pH值对HMF电氧化的影响,系统地总结反应机制(直接和间接氧化);重点概述近5年来过渡金属基电极在HMF电氧化上的研究进展及优缺点;还讨论将HMF电氧化与不同类型的阴极还原相结合以实现更高能源利用的耦合系统.旨在为可再生资源的利用和生产先进的催化电极提供指导.The preparation of value-added chemicals from sustainable biomass resources is of great significance for mitigating fossil fuel depletion.As one of the important bio-based platform molecules from 5-hydroxymethylfurfural(HMF)oxidation,2,5-furandicarboxylic acid(FDCA)has received widespread attention as a sustainable alternative to petroleum-derived terephthalic acid(TPA).Compared with the traditional thermocatalytic conversion,electrochemical catalysis has the advantages of environmental friendliness,mild reaction conditions and strong controllability of the reaction system,where use in efficient catalysis of HMF to synthesize FDCA can minimize the energy cost and environmental impact to a large extent.Here,we discuss the electrochemical oxidation of HMF,describe the effect of pH on the HMF electrooxidation,and systematically summarize the reaction mechanism(direct and indirect oxidation).Then,the research progress as well as advantages and disadvantages of transition metal-based electrodes in HMF electrooxidation in the past five years are summarized.In addition,coupled systems that combine HMF electrooxidation with different types of cathodic reduction for higher energy utilization are discussed.The purpose of this review is to provide guidance for the utilization of renewable resources and the production of advanced catalytic electrodes.

关 键 词：5-羟甲基糠醛 2 5-呋喃二甲酸 电化学氧化 过渡金属基催化剂 

分 类 号：TQ352.79[化学工程]