聚苯胺纳米管可控制备的研究进展  

Research Progress in the Controllable Preparation of Polyaniline Nanotubes

作　　者：魏坤 王延敏[1] WEI Kun;WANG Yanmin(College of Materials Science and Engineering,Shandong University of Science and Technology,Qingdao 266590,China)

机构地区：[1]山东科技大学材料科学与工程学院,山东青岛266590

出　　处：《福建师范大学学报(自然科学版)》2025年第3期65-71,共7页Journal of Fujian Normal University:Natural Science Edition

基　　金：山东省自然科学基金项目(ZR2012EMQ002)。

摘　　要：聚苯胺纳米管是一种由聚苯胺分子组合而成的纳米级别管状结构,具有高长径比、高孔隙率、超疏水性、高温稳定性及良好的导电性等优异的性能。介绍了聚苯胺纳米管的制备方法,系统梳理了聚苯胺纳米管微观形貌的可控制备,详细阐述了形态控制剂、反应时间、苯胺单体浓度、反应温度、过硫酸铵浓度等聚合反应条件对聚苯胺纳米管形貌的影响,并介绍了聚苯胺纳米管在储能方面的应用。Polyaniline nanotubes are nanoscale tubular structures composed of polyaniline molecules.They exhibit excellent properties such as a high aspect ratio,high porosity,super hydrophobicity,high-temperature stability,and good electrical conductivity.This paper presents the preparation methods of polyaniline nanotubes and systematically reviews the controllable synthesis of their morphology.The effects of polymerization conditions—such as morphology-controlling agents,reaction time,aniline monomer concentration,reaction temperature,and ammonium persulfate concentration—on the morphology of polyaniline nanotubes are described in detail.In addition,their application in energy storage is briefly discussed.

关 键 词：聚苯胺 纳米管 微观形貌 可控制备 聚合反应条件 储能 应用 

分 类 号：O631[理学—高分子化学]