共轭微孔聚合物的合成、制备及其在污染物处理中的应用  

Synthesis, Preparation, and Application of Conjugated Microporous Polymers in Contaminant Adsorption

作　　者：刘智明 孙平川[1] LIU Zhi-ming;SUN Ping-chuan(Key Laboratory of Function Polymer Materials,Ministry of Education,Institute of Polymer Chemistry,College of Chemistry,Nankai University,Tianjin 300071,China)

机构地区：[1]南开大学化学学院高分子化学研究所,功能高分子材料教育部重点实验室,天津300071

出　　处：《离子交换与吸附》2025年第2期114-128,I0002,共16页Ion Exchange and Adsorption

摘　　要：吸附法是用于污染物处理最常见的方法,被广泛运用于空气和水资源的污染处理。作为多孔有机聚合物的典型代表,共轭微孔聚合物(CMPs)由具有共轭效应的芳香基团通过共价键连接形成。CMPs不仅将优异的孔隙特性与共轭结构完美地结合起来,而且具有较高的稳定性和多样化的合成策略,已被广泛应用于污染处理和能源转化等领域。文章综述了CMPs的合成和制备方法,并介绍了CMPs在污染物处理中的应用,特别是CMPs对二氧化碳和碘蒸汽等气体污染物的吸附以及水体中重金属等污染物处理的研究进展,最后总结并概述了该领域未来的研究和发展方向。Adsorption is the most common method used for contaminant management and is widely applied in the management of air and water pollution. As a typical representative of porous organic polymers, conjugated microporous polymers(CMPs) are formed by bonding of aromatic groups with conjugation effect. CMPs not only exhibit excellent pore properties with extended conjugation system, but also have high stability and diversified synthesizing strategies, which have been widely used in energy conversion and pollution adsorption. This paper reviews the synthesis and preparation methods of CMPs, and introduces the application of CMPs in pollutant treatment, discusses the progress of adsorption studies of gaseous pollutants on carbon dioxide and iodine vapors as well as the progress of studies on pollutants such as heavy metals in the water body, and finally summarizes and proposes the direction of the subsequent research in this field.

关 键 词：共轭微孔聚合物 吸附性能 污染物处理 聚合后修饰 结构-性能关系 

分 类 号：O634[理学—高分子化学]