PVK/SiO_2纳米粒子复合体系能量传递的研究  

Energy Transfer of PVK/SiO_2 Nanometer Combination System

作　　者：安利民[1] 单桂晔[1] 王新[1] 刘益春[1] 孔祥贵[1] 

机构地区：[1]中国科学院长春光学精密机械与物理研究所激发态物理重点实验室

出　　处：《发光学报》2002年第6期590-594,共5页Chinese Journal of Luminescence

基　　金：国家自然科学基金资助项目(19974048)

摘　　要：通过溶胶反应在乙醇溶液中合成了60nm的SiO2纳米粒子,将其与聚乙烯咔唑(PVK)共混,得到了不同质量分数的PVK/SiO2复合体系。利用荧光光谱、吸收光谱,研究了PVK/SiO2复合体系的荧光效应,光致发光的研究表明在PVK与SiO2纳米粒子之间存在界面能量传递过程,这种能量传递的必要条件是PVK的发射谱与SiO2纳米粒子的吸收谱有重叠。以上研究表明PVK/SiO2复合体系存在较强的界面效应,是研究有机与无机纳米体系界面效应的良好模型。Poly(9vinylcarbazole) (PVK) is a typical holetransporting polymer and is often used as a host in electroluminescence devices.In this paper, Frster energy transfer from organic molecules (PVK) to inorganic nanoparticles ( SiO2) was discussed. SiO2 nanoparticles, which are confirmed to be 60nm using transmission electron microscope (TEM), have been synthesized by sol. The structure scheme of poly (9vinylcarbazole) (PVK) molecule is shown firstly. The emission of luminescence is the result from π*π transition of π electrons. Photoluminescence (PL) spectra of the PVK/SiO2 composite film on Si substrates were employed to study the interface effect. In the PL spectra of PVK molecules, three obvious peaks (417, 458, 495nm ) can been seen. The emission of 417nm comes from free exciton. The emission of 458nm comes from bound exciton. And the emission around 495nm is correlated to surface defect states. The intensity of shortwavelength emission (about 400nm) is higher than that of visible luminescence (about 495nm). Two luminescence peaks can be observed in the PL spectra of 60nm SiO2 nanoparticles. In contrast to the PL spectra of PVK molecules, the luminescence intensity about 495nm is higher than that about 400nm in SiO2 nanoparticles PL spectra. Furthermore, UV/Visible absorption spectroscopy of 60nm SiO2 nanoparticles was measured. The spectrum indicates that the scale of absorption is wide enough from 200nm to 500nm. The ratio of PVK to SiO2 in the composite was increased orderly in weight. In the PL spectra of different concentration composite films, we found that Frster energy transfer occurred between PVK and SiO2 nanoparticles. Overlap is observed between the UVVisible absorption spectrum of the SiO2 nanoparticles and the emission spectrum of PVK molecules. We suggest that this overlap is the necessary condition of Frster energy transfer. Further investigation indicates that 40% (the content of PVK in composite in weight) is regarded as an opti

关 键 词：PVK/SiO2复合体系薄膜 能量传递 光致发光 纳米粒子 荧光效应 界面效应 

分 类 号：O484.41[理学—固体物理] TB38[理学—物理]